Electrical discharges in liquids are considered an efficient and ecological technique of nanoparticle synthesis via controlled erosion electrodes. Herein, we use spark between Co–Co, Ni–Ni, Co–Ni, or Ni–Co electrodes immersed distilled water to synthesize Co and/or Ni nanoparticles, as well their oxides. When mixed used (Co–Ni Ni–Co), both nanoparticles produced, the major species is dictated b...