High-quality one-dimensional WO3/CdS core/shell nanowire arrays used as photoanodes in photoelectrochemical (PEC) cells were for the first time prepared via a rational, two-step chemical vapor deposition process. The narrow band-gap CdS shell was homogeneously coated on the entire surface of as-grown WO3 core nanowire arrays, forming coaxial heterostructures. The one-dimensional core/shell hete...

In this research, WO3 and Au-WO3 thin films were prepared at different temperatures using the sol gel method. The effect of gold nanoparticles (GNPs) on the electrochromic properties of WO3 was also studied. 2.5 nm GNP was synthesized through sodium citrate reduction of gold chloride in an aqueous solution. These films were characterized by XRD, SEM, TEM, and spectrophotometer analyses. The fil...

In this chapter, various synthesis routes for PZT powders and fabrication processing techniques for PZT ceramics and films are reviewed. Emphasis is placed on chemical routes, especially the hydrothermal synthesis of PZT powders. The principles of the colloidal chemistry in ceramic suspension and its application to the colloidal processing of ceramics and films, especially when using sub-micron...

Alumina nanopowders produced by electrical explosion of wires were sintered using the spark plasma sintering technique. The results of XRD analysis show that the main phase in the compacted nanopowders is α-Al2O3. According to the SEM observations, the sintered alumina nanopowder consists of micron-sized faceted grains and nano-sized necked grains. The increase in sintering temperature resulted...

We have developed a method of biochemical patterning which allows for micro and nano-scale resolution on non-planar substrates. In this method, bio molecules (including DNA) are delivered to charged locations on surfaces by charged water buffer droplets. Charging of water droplets is accomplished using Dielectric Barrier Discharge (DBD) plasma. DBD was effectively stabilized in the presence of ...

A series of model-supported WO3 catalysts were synthesized on preformed Al2O3, Nb2O5, TiO2, and ZrO2 supports by impregnation of aqueous ammonium metatungstate, (NH4)10W12O41·5H2O. The molecular and electronic structures of the supported tungsten oxide phases were determined with in situ Raman and UV–vis spectroscopy, respectively. The supported tungsten oxide structures are the same on all oxi...

The goal of this study is to characterize the Raman spectra of tungsten trioxide (WO3) at increasing temperatures in the range 30.6–170 ̊C in order to understand the behavior and characteristics of WO3 after adsorption of toxic gases (e.g. NO and SO2) and to provide a database of Raman spectral features for future use in providing an optical complement to semi-conducting metal oxide gas sensor t...

In this paper, we have studied Fe-doping of nanostructured tungsten trioxide (WO3) and its pronounced effect in promoting the photoelectrochemical (PEC) water splitting performance. Vertically aligned Fe-doped WO3 nanoflakes on fluorine-doped tin oxide (FTO) were synthesized via the hydrothermal method. An X-ray photoelectron spectroscopy (XPS) analysis confirmed the Fe(3+) substitution at the ...

Increasing demand for nano-scale machining processes in the semiconductor industry necessitates new mechanisms for nano-machining. A system capable of nano-scale machining of conductive material via Electronic Pen Lithography (EPL) may fit this niche. The purpose of this research is to develop a system capable of EPL based on a HexFlex six axis nano-manipulator. The system will also be capable ...

We report on the fabrication of photo-patterned structures with sub-micron feature sizes in a sol-gel derived organic-inorganic hybrid material. Patterns with a high level of design complexity are presented, in the form of a diffractive optically variable device. We also demonstrate how the material can serve as a matrix for nano-scale components, via the incorporation of Ag nanoparticles. It i...