Nanosphere lithography, an inexpensive and high throughput technique capable of producing nanostructure (below 100 nm feature size) arrays, relies on the formation of a monolayer of self-assembled nanospheres, followed by custom-etching to produce nanometre size features on large-area substrates. A theoretical model underpinning the self-ordering process by centrifugation is proposed to describ...

Most model lung surfactant (LS) monolayer (DPPC:POPG 7:3) work is done at room temperature, far below the physiological 37C. The reason for this is often that in addition to the experimental difficulties of working at higher temperatures, also model LS monolayers are highly fluid and unstable at these temperatures. Fluid monolayers collapse by flowing into the subphase through vesicles or disks...

We report the results of new grazing incidence X-ray diffraction studies of Langmuir monolayers of F(CF~)jjCOOH and F(CF~)jOCH~COOH supported on water in each case the locations and intensities of the first three diffraction peaks ((1, 0), (1, 1) and (2, 0)) have been measured. These new data are consistent with earlier ones in that both monolayers have simple hexagonal packing of molecules wit...

The effects of lateral tension on the properties of membranes are often explained in comparison with analogous experiments on monolayers, which yield more detailed data. To calculate the effects of changes in tension on the composition of, or incorporation of amphiphiles into membranes we examine (i) the fidelity of the monolayer analogy, (ii) the range of possible tensions in a membrane, and t...

Modifying the chemistry of a surface has been widely used to influence interfacial properties of a material or nature of interaction between two materials. This article provides an overview on the role of polyfunctional molecules, specifically silanes, in surface modification of polar surfaces (bearing soft nucleophiles). An emphasis on the mechanism of the reaction in the presence of adsorbed ...

One of the most important functions of the lung surfactant monolayer is to form the first line of defence against inhaled aerosols such as nanoparticles (NPs), which remains largely unexplored. We report here, for the first time, the interaction of polyorganosiloxane NPs (AmorSil20: 22 nm in diameter) with lipid monolayers characteristic of alveolar surfactant. To enable a better understanding,...

The effects of zinc oxide nanorod on the barrier, sorption isotherm and antibacterial properties of tapioca starch/bovine gelatin Bionanocomposite films were investigated. The nanorod-rich ZnO (ZnO-N) was homogenized by sonication and incorporated into tapioca starch/bovine gelatin solutions at different concentrations (e.g. 0.5, 2, and 3.5% w/w dried solid). Incorporation of 3.5% of nanopartic...

Photoinduced electron transfer (PET) has been investigated in organized monolayers at the air-water interface and in monolayer assemblies on glass in an effort to evaluate the influence of solvent reorganization and molecular dynamics on PET. The donor monolayer contained an amphiphilic thiacyanine dye, and the electron acceptors were methyl viologen and dioctadecyl viologen, respectively. The ...