The present study investigates the transesterification of corn oil with methanol over two oxides of MgO and ZnO at 65 ͦC and 1 atm. These two catalysts have been prepared via a conventional co-precipitation process. As for MgO, the corresponding mixed metal nitrate solution has been mixed and heated at the presence of urea. ZnO has also been synthesized by co-precipitation of metal acetate at th...

We demonstrate that configurational electronic entropy, previously neglected, in ab initio thermodynamics of materials can qualitatively modify the finite-temperature phase stability of mixed-valence oxides. While transformations from low-T ordered or immiscible states are almost always driven by configurational disorder (i.e., random occupation of lattice sites by multiple species), in FePO4-L...

Metal propionate hydrazinates, M (CH3CH 2COO)2 (N 2H4 )2 where M = Mn, Co, Ni, Zn or Cd, and mixed metal propionate hydrazinates with cobalt, M i^Q ^^C H ^C I-^C O O ^^I-L t^ where M = Mg, Mn, Ni, Zn or Cd, have been prepared and characterized by analytical, magnetic, spectral, thermal and X-ray diffraction studies. The thermal decomposition of the former complexes yields the metal oxides while...

Ex-situ catalytic fast pyrolysis (CFP) was employed to produce bio-oils from beech wood. The effect of Nb-based mixed oxides (with second metal oxide = W, Al or Mn) in upgrading the vapors compared an H-ZSM-5 catalyst and non-catalyzed pyrolysis. catalysts acidic properties were assessed by NH3-TPD FTIR adsorbed pyridine. obtained characterized Karl-Fischer titration, GPC, CHNS analyses, 13C-NM...