A new type of radionuclide extraction material is reported based on phosphonate functionalities covalently anchored on the mesopore surface of 3-D cubic mesoporous silica (KIT-6). The easily prepared nanoporous hybrid shows largely superior performance in selective sorption of uranium and thorium as compared to the U/TEVA commercial resin and 2-D hexagonal SBA-15 equivalent.

A Co(3)O(4) monolayer hollow-sphere array with mesoporous walls exhibits high pseudocapacitances of 358 F g(-1) at 2 A g(-1) and 305 F g(-1) at 40 A g(-1), as well as excellent cycling stability for application as pseudocapacitors.

632 Ó WILEY-VCH Verlag GmbH, D-69469 Weinheim, 1999 0935-9648/99/0806-0632 $ 17.50+.50/0 Adv. Mater. 1999, 11, No. 8 After this the polymer was rigid and could be peeled off carefully from the silicon master. The suspensions were prepared by adding powder to distilled water under constant stirring. The pH was always kept between 4 and 5 by dropwise adding a 2 M solution of hydrochloric acid (Ti...

A transmission electron microscope was used to characterize a powder form of hexagonally-ordered mesoporous silica material. The structural symmetry built into this amorphous material allowed one to obtain three characteristic images, i.e. a hexagonal honey-comb structure and wide/narrow parallel lines. These images were found to originate primarily from phase contrast, which changed sensitivel...

As a new organic reaction medium, a periodic mesoporous inorganic material was found to function as a "solid solvent" in a Diels-Alder reaction of C(60) with cyclopentadiene. This finding was supported by a concentration effect and a kinetic study of the reaction.

In this study, Santa Barbara Amorphous (SBA-15) mesoporous silica has been functionalized with aminopropyl groups that were converted to propargyl-bearing moieties through the reaction with propargyl bromide. The material then underwent an efficient Cu(I)-catalyzed azide alkyne click reaction with sodium azide in order to obtain the corresponding triazole products. The covalent modification of ...

in  this  study,  amino  functional  groups  were  chemically  bonded  to  the  surface  of  newly synthesized  kit-6  mesoporous  magnetite  nanoparticles  (mmnps)  by  post-toluene  reflux synthesis method.  this method  treats  calcined mesoporous  nanoparticles with  the  functional organosilanes.  physical  and  chemical  structures  of  the  synthesized  mesoporous  magnetite nanoparticle...

BACKGROUND A liquisolid technique has been reported to be a new approach to improve the release of poorly water-soluble drugs for oral administration. However, an apparent limitation of this technique is the formulation of a high dose because a large amount of liquid vehicle is needed, which finally results in a low-dose liquisolid formulation. Silica as an absorbent has been used extensively i...

The thermo-optical properties of coated surface are important for spacecraft thermal control coatings which depend on the optical properties and structure of the coating material. These coatings control the temperature by their capability of outer energy absorption and its emission. The optical properties of pigment can be improved if the pigment contains a high fraction of voids in its structu...