the idea of smart corrosion inhibition is basis on either inhibitor consumption where it is needed or reducing harmful matrix interaction with it. in addition, applying corrosion inhibitor in a coating causes many problems such as loss of inhibition capability, coating degradation, or both. a useful technique to overcome this problem is applying of inert host systems of nanometer dimensions as ...

The low-efficiency cellular uptake property of current nanoparticles greatly restricts their application in the biomedical field. Herein, we demonstrate that novel virus-like mesoporous silica nanoparticles can easily be synthesized, showing greatly superior cellular uptake property. The unique virus-like mesoporous silica nanoparticles with a spiky tubular rough surface have been successfully ...

BACKGROUND The aim of this study was to synthesize Gd(3+)-based silica nanoparticles that conjugate easily with glucosamine and to investigate their use as a nanoprobe for detection of human fibrosarcoma cells. METHODS Based on the structure of the 2-fluoro-2-deoxy-D-glucose molecule ((18)FDG), a new compound consisting of D-glucose (1.1 nm) was conjugated with a Gd(3+)-based mesoporous silic...

Spherical mesoporous silica MCM-41 was synthesized for adsorptive removal of sulfur compounds from fossil fuels using 1mM solution of dibenzothiophene (DBT) in dodecane as model oil. The prepared silica adsorbent has been characterized by nitrogen adsorption-desorption analysis as well as Small Angle X-ray Scattering (SAXS), and transmission and Scanning Electron Microscopy (SEM) methods. R...

A new sorbent has been developed by grafting Hexamethylenetetramine on a mesoporous molecular sieve (SBA-15) by wet impregnation method. This sorbent (Hexamine/SBA-15) has been characterized using N2 physisorption, X-ray diffraction (XRD) at low angles (2θ°) and FT-IR. To investigate the H2S removal capacity of this adsorbent from CH4-containing gas mixtures, the breakthrough tests have been pe...

Transparent free-standing mesoporous silica (MS) films were synthesized from a system of TMOS-Brij-Acid-H2O. The non-ionic surfactants used included Brij 22 (C12EO10OH), Brij 56 (C16EO10OH), and Brij 76 (C18EO10OH). The acids used include HCl, H3PO4, and CF3SO3H. The effect of synthesis parameters on the synthesis and the proton conductivity of mesoporous silica were investigated. The Brij 56/C...

A limited amount and extreme concentration variability of proteomic-related samples require efficient analyte preconcentration and purification prior to the mass spectrometry (MS)-based analysis. Preferably, these steps should be coupled online with chosen fractionation and detection techniques for the minimization of the sample loss. To realize such sample pretreatment, herein, an on-chip soli...

Owing to its simplicity and low temperature conditions, magnesiothermic reduction of silica is one of the most powerful methods for producing silicon nanostructures. However, incomplete reduction takes place in this process leaving unconverted silica under the silicon layer. This phenomenon limits the use of this method for the rational design of silicon structures. In this effort, a technique ...

We apply mesoporous thin silica films with nanometer-sized pores as drug carriers and incorporate the widely used anticancer drug Doxorubicin. Through single-molecule based measurements, we gain mechanistic insights into the drug diffusion inside the mesoporous film, which governs the drug-delivery at the target-site. Drug dynamics inside the nanopores is controlled by pore size and surface mod...