Wettability is an important factor affecting the performance of catalytic oxidative desulfurization. In order to develop efficient catalyst for extractive coupled desulfurization (ECODS) fuel oil by H2O2 and acetonitrile, a novel family imidazole-based polyoxometalate dicationic ionic liquids (POM-DILs) [Cn(MIM)2]PW12O40 (n = 2, 4, 6) was synthesized modifying phosphotungstic acid (H3PW12O40) w...

The properties of lyotropic ferronematic liquid crystals based on new Ni, Cu and Zn ionic magnetic uids are discussed. The eÆciency of these new ferro uids in the lyotropic nematic liquid crystal doping is veri ed and compared with the conventional surfacted ferro uid lyotropic doping. It was observed that the structural characteristics of the lyotropics and ferro uids determine the good format...

α-Amino nitriles are synthesized in a one-pot, three-component coupling of aldehydes (or ketones), aniline, and trimethylsilyl cyanide using a catalytic amount of choline chloride.2ZnCl2 as a bio Lewis acidic ionic liquid. Mild Lewis acidic characteristic of this ionic liquid allows efficient synthesis of α-amino nitriles from acid sensitive aldehydes.

The front cover displays novel ionic liquid crystalline (ILC) compounds containing a nitroxide radical unit in the organic cations, showing an enantiotropic smectic A (SmA) phase. One of ILC shows strong intermolecular magnetic interactions owing to nanosegregation strongly bonded and non-ionic moieties. Its droplet can be magnetically manipulable. More information found Full Paper by Yoshiaki ...

We report the successful preparation of solvent-free metal nanoparticle (NP) fluids with multiple-functionalities, such as rheological properties, magnetism, ionic conductivity, and electrical properties, allowing for facile synthesis and mass production. The gold nanoparticles (AuNPs) used in this study were synthesized using tetraoctylammonium bromide (TOABr) in toluene and then directly phas...

For the first time, a novel and efficient ionic liquid-based ultrasound-assisted in-situ solvent formation microextraction (IL-UA-ISFME) combined with high-performance liquid chromatography-ultraviolet detection (HPLC-UV) has been successfully developed for the determination of duloxetine (DLX) in human plasma. Herein, an environmentally-friendly hydrophobic ionic liquid (1-butyl-3-methylimidaz...

In this study, we combined Ionic Liquid-based Dispersive Liquid Liquid Micro Extraction (IL-DLLME) with FAAS for determining the palladium in different real samples at the trace level. 1-hexyl-3-methylimidazolium hexafluorophosphate [Hmim][PF6] ionic liquid and 1-(2-pyridylazo) 2-naphthol (PAN), were chosen as the extraction solvent and the chelating agent, respectively. The hydr...

zno nanostructures have been synthesized by a simple reflux method, using different ionic liquids, such as 1-benzyl-3-methylimidazolium bromide ([bzmim][br]), 1,1'-(1,4 phenylenebis (methylene)) bis (3-methyl-1h-imidazol-3-ium) bromide ([mm-1,4-dbzim2][br]2) and 1-phenacyl-3-methylimidazolium bromide ([pmim][br]), with different amount of sodium hydroxide in water. also the effect of reaction t...

simple, low temperature and environmentally benign green route is proposed for preparation of nanocrystalline zno in presence of a low-cost and halide-free room-temperature ionic liquid (rtil) by refluxing at 95 °c for 60 minutes. the x-ray diffraction (xrd) studies display that the products are well-crystallized in the form of wurtzite hexagonal. morphology of the as-prepared zno was character...