The interactions between electric field and the mechanical properties of materials are important for the applications of microelectromechanical and nanoelectromechanical systems, but relatively unexplored for nanoscale materials. Here, we observe an apparent correlation between the change of the fractured topography of Nb-doped SrTiO3 (Nb:STO) within the presence of a built-in electric field re...

The electrochemical reduction of oxygen on Lanthanum Manganite(LSM) electrodes has been investigated by cyclic voltammetry, AC impedance and, in particular, potential step. An emphasis was given to the study of the kinetics of the formation of oxygen vacancy, which is shown to be the main cause for the reserved hysteresis in cyclic voltammograms and for the increase in the electrochemical activ...

Particulate iron was found within the trophocytes of the fat body of the adult honey-bee. These iron granules differed in their structure and composition from iron granules found in other biological systems. The granules had an average diameter of 0.32 +/- 0.07 micron and were composed of iron, calcium and phosphorus in a non-crystalline arrangement. The granules were apparently randomly distri...

Supramolecular self-assembly can not only lead to a better understanding of biological systems, but also can enable rational building of complex and functional materials. In this report, hierarchical one-dimensional (1D) architectures involving nanotubes, coiled-coil ropelike structures, nanohelices, and nanoribbons are created via lanthanum-cholate supramolecular self-assembly. These sophistic...

In this work we present the preparation and characterization of cerium doped lanthanum zirconate (LCZO) films and non-stoichiometric lanthanum zirconate (LZO) buffer layers on metallic Ni-5% W substrates using chemical solution deposition (CSD), starting from aqueous precursor solutions. La₂Zr₂O₇ films doped with varying percentages of Ce at constant La concentration (La0.5CexZr1-xOy) were prep...

The RM1 model for the lanthanides is parameterized for complexes of the trications of lanthanum, cerium, and praseodymium. The semiempirical quantum chemical model core stands for the [Xe]4fn electronic configuration, with n =0,1,2 for La(III), Ce(III), and Pr(III), respectively. In addition, the valence shell is described by three electrons in a set of 5d, 6s, and 6p orbitals. Results indicate...