In this work, experimental kinetics data of methane hydrate decomposition at temperatures ranging from 272.15 to 276.15 K and at pressures ranging from 10 to 30 bars were modeled by using chemical affinity. This model proposed a macroscopic model which is independent of any intermediate mechanism like heat or mass transfer. The results show there is good agreement with experimental data. Al...

theaim of the current study was to assess effects of different levels of origanum vulgare (0, 250, 500, 750 and 1000 mg/l) on kinetics of gas production, some ruminal digestion and fermentation parameters, methane production and also to determine its potential in controlling rumen acidosis using in vitro method in four separate phases. in the first phase, the asymptote of gas production (a) and...

CONTEXT Baseball pitching kinematics, kinetics, ball velocity, and injuries at the shoulder and elbow are related. EVIDENCE ACQUISITION PubMed and Sport Discus were searched for original studies published between 1994 and 2008. Relevant references in these studies were retrieved. Inferential studies that tested relationships between kinematics and kinetics were included, as were studies that ...

The current research was focused on synthesizing potassium sodium niobate (KNN) piezoelectric ceramics for the system (K0.48Na0.52) NbO3   by high energy ball milling process for 15h at the speed of 300 rpm.  The blended nano-crystalline powder was calcined in conventional box furnace at 700oC, 800oC and 900oC for duration of 5h, 7h and 10h.  Diffraction result of calcine powder confirmed the f...

The internal microstructure of a tablet, such as pore geometry and volume, impacts the tablet’s disintegration kinetics. Ideally, one could design to control dissolution onset therapeutical performance immediate-release formulas; however, manufacturing tablets with desired can be challenging due interplay between formulation process parameters. Direct quantification tablet provide framework for...

The kinetics and mechanism of the reaction between benzaldehyde 1, malononitrile 2 and dimedone 3 in a mixture of ethanol and water as solvents in the presence of fructose as a biodegradable catalyst has been studied by the spectroscopic method (UV-Vis spectrophotometry method). The influence of various parameters (temperature, solvent and concentration) was studied on the reaction by means of ...

It is a well known fact that, dual fuel engines at part loads, inevitably suffer lower thermal efficiency, higher carbon monoxide and unburned fuel emission. The work in this paper is to investigate combustion characteristics of a dual fuel (diesel-gas) engine at part loads, using a single zone combustion model with detailed chemical kinetics for combustion of natural gas fuel. The authors deve...

the kinetics of iodination of the phenol and substituted phenols using pyridiniumiodochloride in methanol has been studied under varying conditions. the rates show first orderkinetics each in pyridinium iodochloride and phenols. the rates of reactions are measured atdifferent temperature and activation parameters for all phenols computed. hammett plot is foundto be valid and the corrletion betw...