classical trajectory (monte carlo) calculation is used to calculate collision rate constants of ion-quadrupolar molecule interactions for the h¯+c2h2 system. the method presented here takes into account the effect of the induced dipole-induced dipole potential on ion-quadrupolar molecule collision rate constants. it is also assumed that the colliding particles have a definite size. the thermal ...

high strength fresh leachates generated at a new disposal trench, compost plant and partially stabilized leachate of an older trench were characterized in terms of anaerobic degradation at laboratory batch scale at 35oc. fresh leachate had extremely high cod of 66,710 – 89,501 mg/l along with low ph of 4.1-5.9 in contrast to older and therefore partially stabilized leachate with a cod of about ...

We evaluate the large-scale energy budget of magnetic reconnection utilizing an analytical time-dependent impulsive reconnection model and a numerical 2-D MHD simulation. With the generalization to compressible plasma, we can investigate changes in the thermal, kinetic, and magnetic energies. We study these changes in three different regions: (a) the region defined by the outflowing plasma (out...

7 Abstract 8 A systematic investigation of the thermal decomposition of viscoelastic memory 9 foam (VMF) was performed using thermogravimetric analysis (TGA) to obtain the 10 kinetic parameters, and thermogravimetric analysis coupled to Fourier Transformed 11 Infrared Spectrometry (TGA-FTIR) and thermogravimetric analysis coupled to Mass 12 Spectrometry (TGA-MS) to obtain detailed information o...

Degradation is a common problem for polymer matrix composites (PMCs) under low thermal cycling conditions. This paper investigates the effects of low thermal cycling on total mass loss (TML) and surface degradation of PMCs. Unnotched and open-hole specimens were weighed before and after low thermal cycling. The total mass loss and surface degradation of the specimens were studied over 250 cycle...

the thermal decomposition of 86 % vinyl chloride 14 % vinyl acetate copolymer wasstudied by the conductometry technique in the presence of nitrogen. the kinetics of stability andthermal degradation of vinyl chloride- co- vinyl acetate (pvc- co- pvac) copolymer withcopper, copper oxide and tricalcium dicitrate (st) were investigated at various temperatures (150-180 oc ) in solution. the rate coe...

The thermal and kinetic aspects of solid state decomposition reactions can be complex and posses a large number of parameters to investigate. The determination of the activation energies for the several intermediates in the thermal decomposition is particularly sensitive to the overlap in thermal decomposition traces. To overcome this problem we have undertaken the detailed kinetic analysis of ...

Kinetic Monte Carlo simulation was applied to investigation of kinetics and mechanism of oxalic acid degradation by direct and heterogeneous catalytic ozonation. La-containing perovskites including LaFeO3, LaNiO3, LaCoO3 and LaMnO3 was studied as catalyst for oxalic acid ozonation. The reaction kinetic mechanisms of each abovementioned catalytic systems has been achieved. The rate constants val...