nanometric carbid silicon (sic) supported monometallic and bimetallic catalysts containing fe, co, ni transition metals were prepared by wet impregnation method. multiwall carbon nanotubes (mwcnts) were synthesized over the prepared catalysts from catalytic decomposition of acetylene at 850°c by thermal chemical vapor deposition (tcvd) technique. the synthesized nanomaterials (catalysts and cnt...

Rational design of high efficient and low cost electrocatalysts for oxygen evolution reaction (OER) plays an important role in water splitting. Herein, a general gelatin-assisted wet chemistry method is employed to fabricate well-defined iron oxy-hydroxides and transitional metal doped iron oxy-hydroxides nanomaterials, which show good catalytic performances for OER. Specifically, the Co-doped ...

O estudo de [Fe(CO)5], [Fe2(CO)9] e [Fe3(CO)12] como precursores catalíticos nas reações de hidrogenação do ciclohexeno e 1-hexeno foi efetuado. Um reator fotoquímico com fluxo de H2 e irradiação UV-vis foi usado no processo. Os espectros infravermelho das amostras mostraram a formação de [Fe(CO)4(olefina)] e [HFe(CO)3(π-alila)] como intermediários. A atividade mostrada do [Fe2(CO)9] na hidroge...

The replacement of noble metal technologies and the realization of new reactivities with earth-abundant metals is at the heart of sustainable synthesis. Alkene hydrogenations have so far been most effectively performed by noble metal catalysts. This study reports an iron-catalyzed hydrogenation protocol for tri- and tetra-substituted alkenes of unprecedented activity and scope under mild condit...

ADVERTISEMENT RETURN TO ISSUEPREVCorrectionNEXTORIGINAL ARTICLEThis notice is a correctionCorrection to “Sustainable Upgrade of Bioderived Glycerol Solketal through Acetalization over Metal-Free Mordenite Catalysts”Bhavna SainiBhavna SainiAcademy Scientific and Innovative Research (AcSIR), Ghaziabad 201002, IndiaLight Stock Processing Division, Council & Industrial Research-Indian Institute Pet...

The effects of confinement in carbon nanotubes on Fischer-Tropsch (FT) activity, selectivity and lifetime of Carbon NanoTubes (CNTs) supported iron catalysts are reported. A method was developed to control the position of the catalytic sites on either inner or outer surface of carbon nanotubes. TEM analyses revealed that more than 80% of iron oxide particles can be controlled to be position...

A detailed investigation was carried out of the effects of porphyrin composition on the activity and selectivity of iron(III) porphyrin catalysts used or the epoxidation of cyclooctene by hydrogen peroxide. Under conditions where the formation of -oxo-dimers can be avoided, the mechanism f cyclooctene epoxidation and hydrogen peroxide decomposition are identical for all of the porphyrin catalys...

The ring-shift isomerization of sym-octahydrophenanthrene (sym-OHP) to sym-octahydroanthracene (sym-OHA) catalyzed by acidic zeolites (Mordenite (MOR) and Faujasite (FAU)) was investigated by the ONIOM(DFT:UFF) and DFT approaches. A "five-membered ring" mechanism through carbocation rearrangement via 1-2 migration was proved to be kinetically favored over a "six-membered ring" mechanism through...

Abstract Fenton processes allow to degrade and mineralize toxic organic contaminants, yet classical require continuously adding hydrogen peroxide ferrous ions, costly solution pH adjustment, treatment of secondary iron sludge pollution. Heterogeneous electro-Fenton deliver oxidizing radicals with only oxygen electricity consumed. Bifunctional catalysts the synthesis activation simultaneously, e...