Green nanotechnology with the goal of producing sustainable nanomaterials in an eco-friendly approach is becoming an increasing necessity for nanomanufacturing industries. In this regards, biosynthesis is well adopted as a viable method for producing benign nanoparticles for biomedical application. The present study aimed at optimization and study of the effects of external stimuli pH and gold ...

Three rapid spectrophotometric methods were developed for the determination of sunitinib based on the formation of ion-pair complex in acidic medium with bromocresol purple, bromothymol blue, and bromophenol blue. The formed ion-pair complexes, extractable with chloroform, were measured at 422 nm for bromocresol purple, 425 nm for bromothymol blue and 427 nm for bromophenol blue. All these meth...

The ion atmosphere around nucleic acids critically affects biological and physical processes such as chromosome packing, RNA folding, and molecular recognition. However, the dynamic nature of the ion atmosphere renders it difficult to characterize. The basic thermodynamic description of this atmosphere, a full accounting of the type and number of associated ions, has remained elusive. Here we p...

Three rapid spectrophotometric methods were developed for the determination of sunitinib based on the formation of ion-pair complex in acidic medium with bromocresol purple, bromothymol blue, and bromophenol blue. The formed ion-pair complexes, extractable with chloroform, were measured at 422 nm for bromocresol purple, 425 nm for bromothymol blue and 427 nm for bromophenol blue. All these meth...

Five rare earth complexeslanthanum(III),praseodymium(III),neodymium(III), samarium(III) and europium(III) have been synthesized from Schiff base ligand (N,N-bis (2-hydroxy-1-naphthylidene) acetylhydrazone). The complexes were characterized based on elemental analysis, molar conductance, ultraviolet, infrared, mass, thermogravimetric and powder X-ray diffraction studies. Infrared spectra sug...

A new sensitive and selective spectrophotometric method for the determination of iron using a PVC membrane containing bathophenanthroline and dioctylphethalate as the solid phase extraction medium is investigated. Fe(II) in an aqueous sample solution is trapped on the membrane with an anion species, picrate ion and forms a complex with bathophenanthroline. The absorbance of the red-orange m...

A cloud point extraction process using the nonionic surfactant Triton X-114 to extracturanium from aqueous solutions was investigated. The method is based on the complexationreaction of uranium with Arsenazo III and micelle-mediated extraction of the complex. Theoptimal extraction and reaction conditions (e.g., pH, reagent concentration, effect of time) werestudied, and the analytical character...

Ion association of the ionic liquid [bmim][Cl] in acetonitrile and in water was studied by dielectric spectroscopy for salt concentrations c ≤ 1.3 M at 298.15 K and by measurement of molar electrical conductivities, Λ, of dilute solutions (c ≤ 0.006 M) in the temperature range 273.15 ≲ T/K ≤ 313.15. Whilst acetonitrile solutions of [bmim][Cl] exhibit moderate ion pairing, with an association co...