phenol and its homologues are aromatics containing hydroxyl, methyl, amide and sulphonic groups attached to the benzene ring. these molecules are both anthropogenic and xenobiotics. phenols are environmental pollutants discharged through wastewaters from various industries. phenols are toxic to several biochemical reactions. however biological transformation of phenols to non-toxic entities exi...

in this work, styrene removal from wastewater by using sugarcane waste (bagasse) as an adsorbent was studied. equilibrium isotherms and kinetics were determined; the effects of bagasse particle size and concentration, solutions ph, and temperature on the biosorption of styrene were studied in batch experiments. adsorption equilibrium data was successfully fitted to langmuir isotherms (r2=0.986)...

kinetic parameters of the ammonolysis reaction of dichloroethane in nonaqueous media are studied and the optimum reaction conditions are reported. a suitable reactor for running the reaction under high pressure in the range of 50 to 500 °c is designed. kinetic behaviours of the system is studied and other reaction parameters such as rate constant, kinetic order, and activation energy are determ...

Mg₂Ni-type Mg₂Ni1-xCox (x = 0, 0.1, 0.2, 0.3, 0.4) alloys were fabricated by melt spinning technique. The structures of the as-spun alloys were characterized by X-ray diffraction (XRD) and transmission electron microscopy (TEM). The hydrogen absorption and desorption kinetics of the alloys were measured by an automatically controlled Sieverts apparatus. The electrochemical hydrogen storage kine...

Practical hydrogen storage for mobile applications requires materials that exhibit high hydrogen densities, low decomposition temperatures, and fast kinetics for absorption and desorption. Unfortunately, no reversible materials are currently known that possess all of these attributes. Here we present an overview of our recent efforts aimed at developing a first-principles computational approach...

The effects of different proportions La and Y elements in the A-side on structure properties A2B7-type La–Y–Ni hydrogen storage alloys were investigated. (La,Y)2Ni7 with La/Y ratios prepared by sintering Y2Ni4 precursor AB5-type precursors at 1298 K for 5 h subsequently annealed 20 1248 K. All only contain Ce2Ni7 (2H-type) Gd2Co7 (3R-type) phases mass ratios. As ratio decreases, cell volume two...

X-ray diffraction studies have been performed on Li-based complex hydrides after multiple hydriding/dehydriding pressure cycles. The effects of pressure cycling are important for longterm reliability of Li-based hydrides. Commercial grade hydrogen containing low-level impurities (O2, H2O, CO/CO2) was used for this study to show the effect of cycling on hydrogen storage capacities. Equilibrium i...

We examined the catalytic effect of nanoparticle 3d-transition metals on hydrogen desorption (HD) properties of MgH(2) prepared by mechanical ball milling method. All the MgH(2) composites prepared by adding a small amount of nanoparticle Fe(nano), Co(nano), Ni(nano), and Cu(nano) metals and by ball milling for 2 h showed much better HD properties than the pure ball-milled MgH(2) itself. In par...

a model describing the main processes occurring in the uasb reactor was developed; in orderto maintain simplicity and applicability of the model, only the fundamental aspects were considered. in themodel, the reactor is divided in several well-stirred reactors coupled in series and it comprises substratedegradation, biomass growth and the reactions that take place within the granules. the impor...