a new tris-chelate cd(ii) complex, [cd(dadmbtz)3](clo3)2 has been successfully synthesized and characterized by ir, 1h, 13c nmr spectroscopy, elemental analysis and single crystal x-ray determination. the thermal behavior, uv-vis and fluorescence spectra of compound were studied. in reaction with dadmbtz, cadmium (ii) forms a tris-chelate complex with nearly c3 symmetry for coordination polyhed...

the internal structure of dna-ctab and dna-ddab is investigated by a small angel x- ray scattering(saxs) instrument. hexagonal packing of dna was observed for dna complex with ctab, and for ddabcomplex is observed lamellar structure. variations in the internal spacing and degree of long-range ordering aredependent on both surfactant type and concentrations of added salt. when we increased the a...

conclusions the diagnosis of thrombocytosis is not easy in all cases. the coexistence of anca and the immune complex in cgn may cause a severe inflammatory state, leading to extreme rt. the roles that the immune complex and anca play on the effect of the platelet count and function in cgn need further research. introduction we describe a female patient with extreme reactive thrombocytosis (rt) ...

‎in this paper‎, ‎we give some necessary conditions for a complex‎ ‎difference equation of malmquist type‎ $$‎sum^n_{j=1}f(z+c_j)=frac{p(f(z))}{q(f(z))}‎,$$ ‎where $n(in{mathbb{n}})geq{2}$‎, ‎and $p(f(z))$ and $q(f(z))$ are‎ ‎relatively prime polynomials in $f(z)$ with small functions as‎ ‎coefficients‎, ‎admitting a meromorphic function of finite order‎. ‎moreover‎, ‎the properties of finite o...

stereoisograms of octahedral complexes are classified into five types (type i--typev) under the action of the corresponding rs-stereoisomeric group. their enumeration is accomplished in a type-itemized fashion, where fujita's proligand method developed originally for combinatorial enumeration under point groups (s. fujita, theor. chem. acc., 113, 73--79 (2005)) is extended to meet the requireme...

several novel mononuclear zn(ii) complexes, [zn(bpy)l2], where bpy=2,2’-bipyridine and l=monoanions of phenylcyanamide (pcyd), 4-methylphenylcyanamide (4-mepcyd), 3,5-dimethylphenylcyanamide(3,5-me2pcyd),4-methoxyphenylcyanamide(4-meopcyd), 3,5-dimeth-oxyphenylcyanamide (3,5-meo2pcyd), 3-chlorophenylcyanamide (3-clpcyd), 2,3-dichlorophenyl-cyanamide (2,3-cl2pcyd), 4-bromophenylcyanamide (4-brpc...

the interaction between 4, 7, 13, 16, 21, 24 - hexaoxa-1,10 - diazabicyclo [8.8.8] hexacosane (c222) and 7,7,8,8- teracyanoquinodimethane (tcnq) has been studied in chloroform at 25°c. the results indicate a two step mechanism. at the first step, two adducts (assign as p1 and p2) are formed through equilibrium reactions. in continue and through nonequilibrium reactions the adducts are converted...