نتایج جستجو برای: hantzsch condensation
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In this study, multi component Hantzsch reaction was carried out between various Aromatic Aldehyde with Dimedone,Ethyl acetateand ammonium acetate to produce polyhydroquinolinederivatives under solvent-free conditions at 110oC by a (Zinc oxide nanocatalyst) as effective Lewis acid. The remarkable advantages offered by this method compared with other methods are a green catalyst, simple work-u...
a simple and mild one-pot three-component reaction for the preparation 1,4-dihydropyridines has been developed from various aldehyde substrates, 1,3-dicarbonyl compounds (dimedone) and ammonium acetate (hantzsch method) in the presence of a catalytic amount of phospho sulfonic acid (psa) as an efficient and heterogeneous solid acid in etoh at room temperature. preparation of psa is straightforw...
Complex chemical reactions can occur in electrosprayed droplets on the millisecond time scale. The Hantzsch synthesis of 1,4-dihydropyridines was studied in this way using on-line mass spectral analysis to optimize conditions and characterize the product mixture. Changing the distance between the nanospray source and the MS inlet allowed exploration of reaction progress as a function of droplet...
We introduce two generalized condensation principles: Local Club Condensation and Stationary Condensation. We show that while Strong Condensation (a generalized Condensation principle introduced by Hugh Woodin in [19]) is inconsistent with an ω1-Erdős cardinal, Stationary Condensation and Local Club Condensation (which should be thought of as weakenings of Strong Condensation) are both consiste...
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