نتایج جستجو برای: guest
تعداد نتایج: 14483 فیلتر نتایج به سال:
We use recently developed procedures to decompose German Lorenz curves for post-government incomes among East Germans, West Germans, and foreign guest workers after German unification. The decomposed Lorenz ordinates permit us to construct interdistributional Lorenz curves, which in turn allow dominance comparisons of changes in economic advantage in different years. Using interdistributional G...
Nanoporous host materials giving rise to transient guest profiles of cylindrical symmetry during molecular uptake and release are shown to provide particularly advantageous conditions for the study of guest diffusion by micro-imaging. Considering zeolites of structure type DDR (Deca-dodecasil 3R) as a host system and short-chain length hydrocarbons as guest molecules, the benefits thus attainab...
Few methods currently exist for controlling vesicle-vesicle adhesion. We now report a new system, based upon a multivalent guest and an amphiphilic receptor with a photo-isomerisable anchor that can be incorporated into lipid vesicles of different sizes. Large unilamellar vesicles containing our receptor were found to aggregate upon addition of the multivalent guest, independently of photoswitc...
Adaptive agents provide a natural and clean way to deal with heterogeneous, distributed and unpredictably evolving environments, such as Internet. In this paper, we present a model of agents that are able to adapt themself to their environment by several ways. Using a middleware approach, our agents, called Guest, can run, communicate and move between different multiagent platforms, which are a...
Molecular clips possessing U-shaped cavities have been functionalized on their convex side with long aliphatic tails. These molecules form dimers which self-assemble into malleable lamellar thin films. Upon addition of a guest (methyl 3,5-dihydroxybenzoate), a 1:1 host-guest complex is formed, which prohibits clip dimerization. As a result, the lamellar structure of the material is lost. Comple...
Complexation of a cis-protected palladium ion and a family of exo-bidentate and -tridentate ligands results in the formation of an equilibrium mixture of numerous metal-linked receptors that are referred to as a dynamic receptor library. We found that a guest induced the selective formation of the optimal receptor of its own. Screening of the library by using difference NMR facilitates the sear...
Gated molecular encapsulations, with baskets of type 1, are postulated to occur by the mechanism in which solvent molecule penetrates the inner space of 1, through one of its apertures, while the residing guest simultaneously departs the cavity. In the transition state of the exchange, three pyridine-based gates are proposed to assume an open position with both incoming solvent and departing gu...
Single molecule (SM) methods are able to resolve structure related dynamics of guest molecules in liquid crystals (LC). Highly diluted small dye molecules on the one hand explore structure formation and LC dynamics, on the other hand they report about a distortion caused by the guest molecules. The anisotropic structure of LC materials is used to retrieve specific conformation related propertie...
The relaxation times r of the slowest processes in the parallel dielectric permittivity of various nematic guest-host systems have been measured as a function of temperature. A correlation between r and its temperature dependence is found, indicating increasing temperature dependence for increasing T, independent of structural details of the guest molecules or properties of the host matrices wh...
Three polarized aromatic guest molecules (pyrene-4,5-dione, 1) form a triple-layered stack in the box-shaped cavity of an organic pillared coordination cage in water. The cavity size strictly limits the number of stacked planar guests but does not restrict guest orientation, and thus enables the study of discrete stacks of polarized guests and their preferred conformations. Crystallographic stu...
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