A process model for pressurised fluidised-bed gasification of biomass was developed using Aspen Plus simulation software. Eight main blocks were used to model the fluidised-bed gasifier, complemented with FORTRAN subroutines nested in the programme to simulate hydrocarbon and NH3 formation as well as carbon conversion. The model was validated with experimental data derived from a PDU-scale test...

In the current study a series of pyrolysis and CO2 gasification experiments were conducted on a bed of kraft black char under a perpendicular impinging jet. The experiments demonstrated that the char bed carbon gasification rates are externally mass transfer limited. The mass transfer is further decreased by a net molar out-flow caused by the conversion of one mole of reactant CO2 to two moles ...

In recent years significant progress has been made in the development of market applications for hydrogen fuel use in gas turbines. These applications include integrated gasification combined cycle (IGCC) and other types of process/power plants. Development of a new application using gas turbines for significant reduction of power plant CO2 emissions has initiated extensive efforts to expand th...

Gasification is a thermochemical pathways used to convert carbonaceous feedstock into syngas (CO and H2) in deprived oxygen environment. The process can accommodate conventional feedstock such as coal as well as discarded waste including plastics, rubber, and even MSW due to the high reactor temperature of 1000 to 1600oC. Pyrolysis is another conversion pathway yet it is more selective to the c...

Conversion of wet biomass via gasification in supercritical water is a promising technology for the production of hydrogen and methane from renewable resources. The properties of water above the critical point enable reactions for the fast degradation of biomass and generation of a product gas consisting of hydrogen, methane, higher hydrocarbons and carbon dioxide without disturbing sulphurand ...

The current study involves an experimental investigation of the decomposition of various biomass feedstocks and their conversion to gaseous fuels such as hydrogen. The steam gasification process resulted in higher levels of H2 and CO for various CO2 input ratios. With increasing rates of CO2 introduced into the feed stream, enhanced char conversion and increased CO levels were observed. While C...

At high temperatures, the experimental gasification rates of graphitized carbon rods are found to deviate progressively more from their intrinsic gasification rates, aa temperature is increased. This is shown to be caused by the increasing control of the reaction by the rate of transport of carbon dioxide through the internal pores of the carbon rod. The ditTusionalresistance concepts used to c...

BACKGROUND Bio-jet fuels compatible with current aviation infrastructure are needed as an alternative to petroleum-based jet fuel to lower greenhouse gas emissions and reduce dependence on fossil fuels. Cradle to grave life cycle analysis is used to investigate the global warming potential and fossil fuel use of converting poplar biomass to drop-in bio-jet fuel via a novel bioconversion platfor...

For appropriate safety assessment of the disposal of TRU waste, distribution coefficients (Kd) and gasification ratios of C labeled [1, 2-C] sodium acetate (C-NaOAc) were determed by batch sorption tests for 85 Japanese paddy soil samples. The soil studied were from four soil types: Andsol; Gley; Gray lowland; and Yellow. The range of Kd values for all soil samples was from 7.5 to 295.2 mL g , ...