A 78-year-old woman was found dead in her basement. Qualitative screening of available postmortem specimens detected the presence of diltiazem and pentoxifylline. Quantitations were carried out by gas chromatography using nitrogen-phosphorus detection and confirmed by gas chromatography-mass spectrometry with the following results: blood, 0.59 mg/dL diltiazem and 0.63 mg/dL pentoxifylline; urin...

Fourier transform infrared (FTIR) spectroscopy in combination with the partial least squares (PLS) multivariative statistical technique was used for quantitative analysis of the poly(beta-hydroxybutyrate) (PHB) contents of bacterial cells. A total of 237 replicate spectra from 34 samples were obtained together with gas chromatography-determined reference PHB contents. Using the PLS regression, ...

Alkaloid contents in Argemone mexicana cell line AMMiF were analyzed during a 36-day culture cycle. The benzophenanthridine sanguinarine (SA) represented the main alkaloid. Dihydrosanguinarine (DHSA), a SA biosynthetic precursor and a less toxic benzophenanthridine, was also identified, based on chromatographic properties and further confirmed by gas chromatography coupled to mass spectrometry....

The aim of this study was to develop an efficient quantitative method for the determination of acetaldehyde (AA) and formaldehyde (FA) contents in solid and liquid food matrices. The determination of those compounds was validated and performed using gas chromatography-mass spectrometry combined by solid phase micro-extraction after derivatization with O-(2,3,4,5,6-pentafluoro-benzyl)-hydroxylam...

In forest soils on calcareous parent material, carbonate is a key component that influences both chemical and physical soil properties and thus fertility and productivity. At low organic carbon contents, it is difficult to distinguish between organic and inorganic carbon, e.g. carbonates, in soils. The common gas-volumetric method to determine carbonate has a number of disadvantages. We hypothe...

Unconventional reservoirs are keys to oil and gas exploration and development, especially shale gas reservoirs. Discriminated shale gas reservoir lithofacies are, in particular, a primary problem in shale gas reservoir engineering. The mineral composition will affect both absorbed and free gas contents, therefore their identification is important. The mineral composition is one part of lithofac...

Pyrolitic conversion of lignocellulosic biomass, such as switchgrass and other agricultural residues, to bio-fuels is being considered for national energy security and for environmental advantages. Bio-oil, syngas and bio-char were produced and characterized from switchgrass at 400, 500 and 600 0C by pyrolysis. Bio-oil yield increased from 22 to 37%, syn-gas yield increased from 8 to 26%, and b...

OBJECTIVE To identify the contents of ampoules stored items at the WW I Kobarid Museum, Slovenia. Sources and methods: Analysis of ampoules from the Kobarid Museum using pharmacopoeial methods. RESULTS The contents of the unlabelled ampoules were identified as calcium hypochlorite, a decontaminant for mustard gas (Yperite). CONCLUSION The Isonzo front/Soška fronta was opened on May 24 1915 ...

This study was undertaken to elucidate the dominant endogenous gibberellins (GA) and the changes in their levels in germinating barley during malting. Also, a method for determining gibberellins in barley and malt by combined gas chromatography-mass spectrometry (GC-MS) was developed. Endogenous gibberellins in germinating Fuji Nijo I I and Betzes barley were sequentially extracted with ethanol...