The two primary sites of herbicide action in photosynthetic electron transport are the inhibition of photosystem II (PS II) electron transport and diversion of electron flow through photosystem I (PS I). PS II electron transport inhibitors bind to the DI protein of the PS II reaction center, thus blocking electron transfer to plastoquinone. Inhibition of PS II electron transport prevents the co...

Numerical calculations of the free energy of the first electron transfer in genetically modified reaction centers from Rhodobacter (Rb.) sphaeroides and Rb. capsulatus were carried out from pH 5 to 11. The multiconformation continuum electrostatics (MCCE) method allows side chain, ligand, and water reorientation to be embedded in the calculations of the Boltzmann distribution of cofactor and am...

a phosgene-free synthesis of symmetrical n,n'-disubstituted urea by the reaction of aromatic and aliphatic primary amines and urea promoted by  microwave irradiation in the presence of a suitable energy-transfer solvent such as n-n-dimethylacetamide is described.

Two magnetic hole events observed by Polar on 20 May 1996 when it was in the polar cap/polar cusp boundary layer are studied. Low-frequency waves, consisting of nonlinear Alfvén waves and large amplitude (±14 nT peakto-peak) obliquely propagating proton cyclotron waves (with frequency f ∼0.6 to 0.7fcp), accompanied by electric bipolar pulses (electron holes) and electron heating have been obser...

background: understanding of the incident electron energy and angular distributions from clinical electron accelerators (linacs) is important for dosimetry and treatment planning. the most important goals of this study were to evaluate the energy fluence and angular distributions of electron beams from a neptun 10pc linac using the monte carlo (mc) code. materials and methods: the linac electro...

This article introduces tri-cationic hemicyanine dye employed as a visible-light photoinitiator of acrylic monomers polymerization. This dye, in combination with borate anions, was found to be a very effective photoinitiating system. The kinetics of trimethylolpropane triacrylate polymerization was studied by a microcalorimetric method. The photoredox pair concentration, the co-initiator struct...

Nonconjugated dendrimers, which are capable of funneling energy from the periphery to the core followed by a charge-transfer process from the core to the periphery, have been synthesized. The energy and electron donors involve a diarylaminopyrene unit and are incorporated at the periphery of these dendrimers. The energy and electron acceptor is at the core of the dendrimer, which involves a chr...

Graphene oxide sheets (GO) were covalently functionalized with thionine molecules. The obtained hybrid material, Th-GO, was characterized by means of scanning electron microscopy (SEM), Auger electron spectroscopy (AES), Fourier transform infrared spectroscopy (FTIR) and Raman spectroscopy. Subsequently, the interaction of light with the free dye molecules and with dye molecules bound to the gr...

Molecular dynamics simulations of electron and ion transfer reactions near a smooth surface are presented, analyzing the effect of the geometrical constraint of the surface and the interfacial electric field on the relevant solvation properties of both a monovalent negative ion and a neutral atom. The simulations show that, from the solvation point of view, ion adsorption is an uphill process d...