DEVELOPING A TOOLBOX TO PROBE REACTION DYNAMICS WITH STRONGFIELD IONIZATION AND NON-LINEAR ATTOSECOND SPECTROSCOPYbyTHUSHANI N. HERATHMay 2015Advisor: Dr. Wen LiMajor: Analytical ChemistryDegree: Doctor of Philosopy Electronic motions which happen in 10 to 100 of attoseconds are the heartof many processes in nature. Therefore monitoring and extracting details...

Field ionization of trimethylamine and of N,N-dimethylaniline doped into xenon is presented as a function of xenon number density up to the density of the triple point liquid, both at noncritical temperatures and along the critical isotherm. These data exhibit a decrease in the xenon induced shift of the dopant ionization energy near the xenon critical point. The energy of the quasi-free electr...

Field ionization of high-n CH3I Rydberg states doped into argon is presented as a function of argon number density along the critical isotherm. These data exhibit a decrease in the argon induced shift of the dopant ionization energy near the critical point. We show that this decrease is due to the interaction between argon and the quasi-free electron arising from field ionization of the dopant....

This review highlights and critically assesses forensic applications in the developing field of ambient ionization mass spectrometry. Ambient ionization methods permit the ionization of samples outside the mass spectrometer in the ordinary atmosphere, with minimal sample preparation. Several ambient ionization methods have been created since 2004 and they utilize different mechanisms to create ...

background: the monte carlo method is the most accurate method for simulation of radiation therapy equipment. the linear accelerators are currently the most widely used machines in radiation therapy centers. methods: in this work, a monte carlo modelling of the siemens oncor linear accelerator in 6 mv and 18 mv beams was performed. the results of simulation were validated by measurements in wat...

A direct solution of the time-dependent Schrödinger equation ~TDSE! for a two-electron model atom in a strong electromagnetic field is used to extract probabilities for both single and double electron ionization. For three-photon ionization at a moderately strong intensity, the TDSE calculations find single ionization at 62%, single ionization with excitation at 10%, and double ionization at 3%...