In the title mol-ecule, C(21)H(25)NO(2), the dihedral angle between the two benzene rings is 4.8 (2)°. Both the ethyl group of the ester group and one of the ethyl groups attached to the N atom are disordered over two sites, the approximate occupancies being 66:34 and 81:19, respectively. In the cystal structure, there are no direction-specific inter-actions.

DGBA 1 Diethylene Glycol n-Butyl Ether Acetate (CAS# 124-17-4) (Synonyms: Butyl carbitol acetate; Butyl diglycol acetate; 2-(2-Butoxyethoxy)ethanol acetate; 2(2-Butoxyethoxy)ethyl acetate; Acetic acid 2-(2-butoxyethoxy)ethyl ester; Butoxyethoxyethyl acetate; Butyl carbitol acetate; Butyl diethylene glycol acetate; Diethyleneglycol monobutyl ether acetate; Diglycol monobutyl ether acetate; Ektas...

Ethyl esters from uncommon fatty acids, such as valproic, azelaic, and sorbic acids, were chemically synthesized and identified by gas chromatography or liquid chromatography coupled to mass spectrometry. Some properties were evaluated to determine their potential for use as biofuels or in other commercial applications. They have remarkable and pleasant odors and, in the case of ethyl ester in ...

The direct reductive amination of aromatic aldehydes has been achieved with excellent isolated yields (89-96%) using readily accessible Ph(3)PAuCl/AgOTf catalyst along with ethyl Hantzsch ester as hydrogen source under mild reaction conditions.

The photodegradation of Azinphos-ethyl (1) in chloroform and methanol solution has been studied. 3,4-D ihydro-3-m ethyl-4-oxobenzo[d][l,2,3]triazine (3), 3,4-dihydro-4-oxo-benzo[d][l,2,3]triazine (5), 0 ,0-d iethyl-0(3-m ethylbenzo[d][l,2 ,3]triazine-4-yl)phosphate (8), N-methylanthranilic acid (11) (in methanol: methyl ester 12), and sulfur have been isolated and charac­ terized as photoproduc...

The title compound, C(12)H(14)O(6)S, is a dicarboxylic acid diethyl ester of 3,4-ethyl-enedioxy-thio-phene, which is a component of electrically conductive poly(3,4-ethyl-enedioxy-thio-phene) (PEDOT). The ethyl-ene group is disordered over two sites with occupancy factors 0.64 and 0.36. Both the carbonyl groups are coplanar with the thio-phene ring. The mol-ecules form centrosymmetric dimers wi...

Active ester Cp-nitrophenyl ester) hydrolysis and transfer reactions catalyzed by transglutaminase have been studied at pH 7.5 and 0” in the presence of 50 mu Ca++. The initial velocities of appearance of two products of the reactions, $-nitrophenol and N-acylamines, were found to be consistent with a ping pong mechanism in which acyl-enzyme formed from active ester may react with water (hydrol...

In this study, novel condensed 1,4-dihydropyridines bearing cyclopentanone (1-21) or tetrahydrothiophene-1,1-dioxide ring (22-42) with various ester substituents were synthesized via a modified Hantzsch reaction and their calcium channel modulator activities were investigated on isolated rat ileum and rat thoracic aorta. The introduction of a cyclopentanone ring fused to the 1,4-dihydropyridine...

The novel heme prosthetic group of Escherichia colt’ NADPH-sulfite reductase (EC 1.8.1.2) has been identified as an iron tetrahydroporphyrin of the isobacteriochlorin type (adjacent pyrrole rings reduced) with eight carboxylic acid side chains. The number of carboxyl groups was established by the following experiments. Esterification with 14CH30H resulted in incorporation of 7.4 moles of 14C pe...