ABSTRACT: Excess fluoride ion (F) in drinking water causes harmful effects such as dental and skeletal fluorosis. Hence, its concentration in drinking water must not exceed a certain range. This study investigated the removal of F from aqueous solutions with CuO nanoparticles using a range of experimental approaches, including pH, adsorbent dose, contact times, and initial F concentration. The ...

The adsorption of thiolates on Au surfaces employing density-functional-theory calculations has been studied. The dissociative chemisorption of dimethyl disulfide (CH(3)S-SCH(3)) on 14 different Au(hkl) is used as a model system. We discuss trends on adsorption energies, bond lengths, and bond angles as the surface structure changes, considering every possible Au(hkl) with h, k, l ≤ 3 plus the ...

The present study aims at investigating the potential of activated carbon AC prepared from waste cotton fiber for the removal of Acid Dyes from aqueous solutions. The prepared activated carbon was characterized by pore structure analysis, Fourier transforms infrared spectroscopy FTIR. Batch adsorption studies were carried out and the effect of experimental parameters such as pH, initial dye con...

Removal of Fe (II) from aqueous media was investigated using chitosan as the adsorbent in both batch and continuous systems. Batch experiments were carried out at initial concentration range of 10-50 mg/L and temperature range of 20–40˚C. In batch experiments, maximum adsorption capacity of 28.7 mg/g and removal efficiency of 93% were obtained. Adsorption equilibrium data were well-fitted with ...

Irreversible random sequential adsorption (RSA) on lattices, and continuum "car parking" analogues, have long received attention as models for reactions on polymer chains, chemisorption on single-crystal surfaces, adsorption in colloidal systems, and solid state transformations. Cooperative generalizations of these models (CSA) are sometimes more appropriate, and can exhibit richer kinetics and...

methoxy polyethylene glycol modified magnetite nanoparticles (pegmns) were synthesized and were characterized by scanning electron microscopy (sem), vibrating sample magnetometer (vsm), and x-ray diffraction (xrd) . the adsorption of diazinon onto (pegmns) was investigated by uv spectrophotometry at 236 nm, through batch experiments. the effects of adsorbent dosage, solution ph, contact time, s...

Powdered activated carbon (PAC) prepared from Eucalyptus camaldulensis Dehn. bark was tested for its adsorption capacity for Cu(II) and Pb(II). The experiment was conducted to investigate the effects of pH, contact time, initial metal concentration, and temperature. The best adsorption of both Cu(II) and Pb(II) occurred at pH 5, where the adsorption reached equilibrium within 45 min for the who...

The adsorptive characteristics of imidacloprid on magnetic activated carbon (MAC12) in comparison to powdered activated carbon (PAC) were investigated. Adsorption of imidacloprid onto powdered activated carbon and magnetic activated carbon was studied as a function of time, initial imidacloprid concentration, temperature and pH. Pseudo-first-order, pseudo-second-order and intraparticle diffusio...

In this study, nano-TiO2 was employed for the adsorption of chloroform from aqueous solution in batch equilibrium experiments to investigate its adsorption properties. The effects of pH, initial chloroform concentration and nano-TiO2 dosage were also investigated. Optimal conditions for chloroform removal by nano-TiO2 have been then identified. Results of equilibrium experiments showed that the...

Graphene Oxide (GO) nano sheets was synthesized from graphite by Hummers method. The nature and morphology of the GO were characterized using FT-IR, UV-Vis, SEM and XRD analysis. Batch sorption experiments were carried out to remove copper (ii) phthalocyanine-tetrasulfonic acid tetrasodium salt [Cu(tsPc)-4.4Na+] from its aqueous solutions using GO as an adsorbent. Experime...