Perylenediimide functionalized bridged siloxane nanoparticles were prepared by direct hydrolysis and condensation of a perylenediimide silane precursor in the presence of a catalytic amount of tetraethoxysilane (TEOS). The sizes of the particles were controlled by adjusting organotrialkoxysilane, base, and TEOS concentrations. Using this modified Stöber method, we were able to incorporate a hig...

Chiroptical properties (circular dichroism and circularly polarized luminescence) were induced in lanthanide ions by doping silica nanohelices with a chirally arranged siloxane network without any organic mediates.

A nonplasma technique, hot-filament chemical vapor deposition ~HFCVD!, is an alternative method for producing organosilicon films of novel structure. Films are deposited onto room-temperature substrates from the precursors hexamethylcyclotrisiloxane (D3) and octamethylcyclotetrasiloxane (D4) at high rates ~.1 mm/min!. Filament temperature can be used to control film structure, and the limited r...

The organosilicon compounds octamethylcyclotetrasiloxane (D4), decamethylcyclopentasiloxane (D5), and dodecamethylcyclohexasiloxane (D6) are high production volume chemicals that are widely used in household goods and personal care products. Due to their prevalence and chemical characteristics, cyclic siloxanes are being assessed as possible persistent organic pollutants. D4, D5, and D6 were me...

Previous molecular dynamics simulations have shown that compression of silica glass surfaces occurs upon formation of an interface with a model crystal and that a structural change caused by this process is retained after glass and crystal are separated. The remnant structural modification caused by this stress was an increase in the concentration of siloxane bond angles less than 1508 in the n...

Contact lenses (CLs) are of common use and the biocompatibility, topography and mechanical properties of the used materials are of major importance. The objective of this contribution is to apply the AFM in mode Peak Force to obtain surface topography and mechanical characteristics of un-worn CLs of different materials. One material of hydrogel, two of siloxane-hydrogel and one of rigid gas-per...

during the past decade, polymer nanocomposites have emerged relatively as a new and rapidly developing class of composite materials and attracted considerable investment in research and development worldwide.direct machining of polymers can be an option for personalized products and for manufacturing product samples. to obtain high quality products and reduce machining costs, it is very importa...

An excellent gene vector is of great importance for the development of the gene therapy. Gelatin–siloxane nanoparticles (GS NPs) with controlled size and surface charge were synthesized through a two-step sol–gel process for gene vector. In order to increase the efficiency of tumour targeting, HIV-derived Tat peptide and TTA1, a kind of modified RNA aptamer, were further grafted onto GS NPs (GS...

Amphiphilic polymers have recently garnered much attention due to their potential use in drug-delivery and other biomedical applications. A modular synthesis of these polymers is extremely desirable since it offers precise individual block characterization and increased yields. We present here for the first time a modular synthesis of poly(oxazoline)-poly(siloxane)-poly(oxazoline) block copolym...

Burn wound care today has a primary objective of temporary or permanent wound closure. Commercially available engineered alternative tissues have become a valuable adjunct to the treatment of burn injuries. Their constituents can be biological, alloplastic or a combination of both. Here the authors describe the aspects of the development of a siloxane epidermis for a collagen-glycosaminoglycan ...