Photoisomerization of azobenzene derivatives is a versatile tool for devising light-responsive materials for a broad range of applications in photonics, robotics, microfabrication, and biomaterials science. Some applications rely on fast isomerization kinetics, while for others, bistable azobenzenes are preferred. However, solid-state materials where the isomerization kinetics depends on the en...

The dependence of disease risk and age-of-onset on expanded CAG repeat length in diseases like Huntington's disease (HD) is well established and correlates with the repeat-length-dependent nucleation kinetics of polyglutamine (polyGln) aggregation. The wide variation in ages of onset among patients with the same repeat length, however, suggests a role for modifying factors. Here we describe the...

Most motile organisms use sensory cues when searching for resources, mates, or prey. The searcher measures sensory data and adjusts its search behavior based on those data. Yet, classical models of species encounter rates assume that searchers move independently of their targets. This assumption leads to the familiar mass action-like encounter rate kinetics typically used in modeling species in...

The reversible binding kinetics o f atrazine, diuron and ioxynil were measured via their bind­ ing and release parameters during steady state inhibition o f electron transport. The parameters were determined in isolated chloroplasts o f peas and o f triazine-resistant and -susceptible bio­ types o f Chenopodium album using a kinetic model. This model is based on the flash-induced oxygen evoluti...

A key step towards a chemical picture of enzyme catalysis was taken in 1913, when Leonor Michaelis and Maud Menten published their studies of sucrose hydrolysis by invertase. Based on a novel experimental design and a mathematical model, their work offered a quantitative view of biochemical kinetics well before the protein nature of enzymes was established and complexes with substrates could be...

in this paper, experimental data on the drying kinetics of corn in a packed and fluidized bed are presented. experimental research was conducted on a laboratory apparatus. corn was used as a material because of its significance in agriculture and the food industry. an analysis of the influence of the operational parameters (the drying medium velocity i. e. the fluidization number, the drying me...

continuous exposure to high-energy ultrasonic waves depolymerises macromolecules in solutions and produces a permanent reduction in viscosity. different factors affect the efficiency of this ultrasonic depolymerisation. in this work ultrasonic degradation of one commercially important hydrogel based on acrylic acid and acrylamide was carried out in aqueous solution at room temperature (25oc). a...

a type of novel hypercross-linked fiber adsorbent was obtained by sulfonation and cross-linking reaction of polypropylene fiber grafted styrene-divinylbenzene. the aim of the fiber sulfonation and cross-linking method was to prepare rigid three dimensional networks in the entire fiber and change the ion exchange capacity of fiber. the hypercross-linked fiber adsorbent possesses a principally di...

although thallium-201 exercise scintigraphy has been established for the detection of myocardial ischemia and viability, little is known regarding the myocardial thallium-201 kinetics during angioplasty. herein, we report a 77-year old man with angina pectoris, in whom serial myocardial imaging after a single dose of thallium-201 was helpful in identifying not only the culprit lesion and myocar...

laboratory degradation studies were performed in water at ph 4.0, 7.0 and 9.2 using prochloraz (450 ec) formulation at the rates of 1.0 (t1) and 2.0 (t2) î¼g/ml. water samples collected on 0 (2h),3,7,15,30,45,60 and 90 days after treatments were processed for residue analysis of prochloraz by hplc-uv detector. in 60 days, dissipation was 89.12-90.53 % at ph 4.0, 84.10-88.17 % at ph 7.0, and 92....