In the present work, Na+-montmorillonite nanoclay (Na-MMT) was functionalized using 3-aminopropyltrimethoxysilane (3-APTMS) as a coupling agent. The covalent functionalization of MMT was confirmed by Fourier-transform infrared spectroscopy (FT-IR). In the specimen fabrication stage, 5 wt% of pristine MMT or silane-functionalized MMT (f-MMT) were incorporated into an epoxy system and the resulta...

To improve the performance of lead-free piezoelectric composites, functionalization filler particles has been suggested as a successful strategy in several recent reports. The details process, however, are not clear, nor is its influence on dielectric properties composites. This study reports systematic investigation process parameters barium titanate nanoparticles (BTONP) with 3-(trimethoxysil...

Circumtrindene (6, C36H12), one of the largest open geodesic polyarenes ever reported, exhibits fullerene-like reactivity at its interior carbon atoms, whereas its edge carbons react like those of planar polycyclic aromatic hydrocarbons (PAHs). The Bingel-Hirsch and Prato reactions - two traditional methods for fullerene functionalization - afford derivatives of circumtrindene with one of the i...

A new prototype of a Hamilton receptor suitable for the functionalization of inorganic nanoparticles was synthesized and characterized. The hydrogen bonding receptor was coupled to a catechol moiety, which served as anchor group for the functionalization of metal oxides, in particular zinc oxide. Synthesized zinc oxide nanorods [ZnO] were used for surface functionalization. The wet-chemical fun...

Carbon nanotube (CNT) membranes allow the mimicking of natural ion channels for applications in drug delivery and chemical separation. Double-walled carbon nanotube membranes were simply functionalized with dye in a single step instead of the previous two-step functionalization. Non-faradic electrochemical impedance spectra indicated that the functionalized gatekeeper by single-step modificatio...

Boron nitride nanotubes (BNNTs) are functionalized and solubilized in organic solvents such as chloroform, methylene chloride, and tetrahydrofuran by using conjugated poly(p-phenylene ethynylene)s (PPEs) (polymers A and B) and polythiophene (polymer C) via a noncovalent functionalization approach through strong π-π stacking interactions between the conjugated polymers and BNNTs. The functionali...

Three orthogonal cascade CH functionalization processes are described, based on ruthenium-catalyzed CH alkenylation. 1-Indanones, indeno indenes, and indeno furanones were accessed through cascade pathways by using arylacetophenones as substrates under conditions of catalytic [{Ru(p-cymene)Cl2 }2 ] and stoichiometric Cu(OAc)2 . Each transformation uses CH functionalization methods to form C...

The application of C-H functionalization logic to target-oriented synthesis provides an exciting new venue for the development of new and useful strategies in organic chemistry. In this article, C-H functionalization reactions are explored as an alternative approach to access pseudodimeric cyclobutane natural products, such as the dictazole and the piperarborenine families. The use of these str...

In this work, we grow different types of carbon nanotube (CNT) forests directly on AlNbased electroacoustic biosensors and study their functionalization efficiency. CNTs are used to increase the effective surface area of the sensor, pursuing a better sensitivity, without increasing the sensor capacitance. Here we use a general method for CNT bio-functionalization with specific receptors for tar...

We demonstrate that the functionalization of carbon nanotubes dramatically alters their sorption characteristics. The effect of covalent functionalization of multiwalled carbon nanotubes (MWNTs) on the gas phase adsorption and desorption of polar and nonpolar organics is presented. Carboxylation and nitration led to the generation of polar functional groups on the nanotube surface. The derivati...