Fabrication of a monocrystalline silicon based heterojunction film at room-temperature in a time-efficient manner is desirable for energy and environmental considerations. In this report, a gas-solid phase direct elemental reaction (DER) route to realize this aim by firstly depositing an elemental copper layer on a monocrystalline silicon surface followed by a reaction with iodine vapor is desc...

An efficient method for palladium-catalyzed homocoupling reaction of terminal alkynes in the synthesis of symmetric diynes is presented. The results showed that both Pd(OAc)(2) and CuI played crucial roles in the reaction. In the presence of 2 mol % Pd(OAc)(2), 2 mol % CuI, 3 equiv of Dabco, and air, homocoupling of various terminal alkynes afforded the corresponding symmetrical diynes in moder...

A mia madre, il cui amorè e incrollabile certezza.

Metals such as CuI and FeII generate hydroxyl radical (.OH) by reducing endogenous hydrogen peroxide (H2O2). Because antioxidants can ameliorate metal-mediated oxidative damage, we have quantified the ability of glutathione, a primary intracellular antioxidant, and other biological sulfur-containing compounds to inhibit metal-mediated DNA damage caused hydroxyl radical. In the CuI/H2O2 system, ...

PVA/CuI polymer composite samples have been prepared and subjected to characterizations using FT-IR spectroscopy, DSC analysis, ac spectroscopy and dc conduction. The FT-IR spectral analysis shows remarkable variation of the absorption peak positions whereas DSC illustrates a little decrease of both glass transition temperature, Tg , and crystallization fraction, χ, with increasing CuI concentr...

The redox activity of Cu ions bound to the amyloid-β (Aβ) peptide is implicated as a source oxidative stress in context Alzheimer's disease. In order explain efficient cycling between CuII-Aβ (distorted square-pyramidal) and CuI-Aβ (digonal) resting states, existence low-populated “in-between” state, prone bind both oxidation has been postulated. Here, we exploited partial X-ray induced photore...

We propose simple behavioral definitions of comparative uncertainty aversion for a single agent towards different sources of uncertainty. Our definitions allow for the comparison of utility curvature for different sources if the agent’s choices satisfy subjective expected utility towards each source. We discuss how our definitions can be applied to investigate ambiguity aversion in Klibanoff et...

Acknowledgments: This project was undertaken when Xiaolin Xing was visiting University of Pittsburgh and Harvard University in 2000. Xiaolin Xing is grateful to the two universities for using their resources and facilities. We thank the seminar participants in Nanyang Technological University and the Chinese University of Hong Kong for comments. We also thank two anonymous referees for helpful ...

Solvothermal reactions of CuI with four flexible N-heterocyclic ligands, 1,2-bis(4-pyridyl)ethane (bpe), 1,1'-(1,4-butanediyl)bis-1H-benzimidazole (bbbm), 1,1'-(1,4-butanediyl)bis-1H-benzotriazole (bbbt), and 1,1'-(1,5-pentanediyl)bis-1H-benzimidazole (pbbm), afforded four new [Cu(n)I(n)]-based coordination polymers, [Cu3I(mu-I)(mu3-I)(bpe)3]n (1), {[CuI(bbbm)1.5].0.25MeCN}n (2), and [Cu4(mu3-I...