The concentrations of hydroxyl groups located inside and on the surface oxide films of a commercially pure titanium, cp-Ti, a type 316L austenitic stainless steel, SS, and a cobalt-chromium-molybdenum alloy, Co-Cr-Mo, were evaluated using X-ray photoelectron spectroscopy, XPS, and a zinc-complex substitution technique. As a result, the concentrations of the hydroxyl groups detected by the zinc-...

Polymorphic materials which are subjected to an external stress while their temperature is repeatedly cycled about their phase transformation range experience, on average, Newtonian flow, which is driven by the biasing of internal transformation mismatch stresses by the external stress (1). This phenomenon, termed transformation superplasticity, is well documented for metals (as reviewed in Ref...

The present study deals with the properties of five different metals/alloys (Al-12Si, Cu-10Sn and 316L—face centered cubic structure, CoCrMo and commercially pure Ti (CP-Ti)—hexagonal closed packed structure) fabricated by selective laser melting. The room temperature tensile properties of Al-12Si samples show good consistency in results within the experimental errors. Similar reproducible resu...

Introduction: Regenerative therapies using biomaterials require accurate information on interactions between the implanted material and the human body. To improve the process of bone regeneration it is necessary to obtain a better understanding of the influence of the surfaces on the early stages of osseointegration. This work aims to investigate the dynamic interaction between simulated body f...

A patient’s body accepting a bone implant depends not only on the biomaterial used, but also its surface, which allows it to properly interact with cells. Therefore, research has focused improving bioactive and tribological properties of titanium alloys. Commercially pure (cp-Ti) is widely used as biomedical material. However, characterized by unsuitable properties. In this work, yttria-stabili...

The local dry underwater laser welding of cp-Ti, with air as an assisting gas, and in a simulated facility was researched, aiming to find viable economical method for repairing titanium alloy vehicles situ the future. Macro-morphology, microstructure, microhardness cp-Ti welds, function parameters, were experimentally characterized. oxidation hardening behaviors welds also studied detail. It fo...

The interest in electrocrystallization of calcium phosphates (CaP) in general, and of hydroxyapatite (HAp) specifically, results from the promising industrial benefits, unique microstructures, and properties of the deposits produced by this process, and the possible similarity to bone mineralization in vivo. In this paper, our work on electrocrystallization of HAp and octacalcium phosphate (OCP...

Applying empirical alloy parameters (including Mo equivalent), the predicted ground state diagram, and thermodynamic calculations, noble nonequiatomic Ti–Zr–Hf–Nb–Ta–Mo high-entropy alloys for metallic biomaterials (BioHEAs) were designed newly developed. It is found that Moeq valence electron concentration (VEC) are useful design involving BCC structure formation in bio medium-entropy BioHEAs....

This work presents the results of electron-beam welding commercially pure α-Ti (CP-Ti) and Ti6Al4V (Ti64) alloys. The structure mechanical properties formed welded joints were examined as a function power electron beam. beam was set to P1 = 2100 W, P2 1500 P3 900 respectively. X-ray diffraction (XRD) experiments performed in order investigate phase composition fabricated joints. microstructure ...

The mono(cyclopentadienyl)titanium(II) complex CpTiCl(dmpe)2 has been prepared by treating (CpTiCl2)x with n-butyllithium in the presence of 1,2-bis(dimethylphosphino)ethane (dmpe). Subsequent treatment of this titanium(II) species with methyllithium or n-butyllithium affords the alkyl and hydride analogues CpTiMe(dmpe)2 and CpTiH(dmpe)2, respectively. The X-ray crystal structures of CpTiX(dmpe...