In this study, simple, fast and reliable cyclic voltammetry, linear sweep voltammetry, square wave voltammetry and differential pulse voltammetry methods were developed and validated for determination of etodolac in pharmaceutical preparations. The proposed methods were based on electrochemical oxidation of etodolac at platinum electrode in acetonitrile solution containing 0.1 M lithium perchlo...

We propose a mixture model for blind source separation and deconvolution with adaptive source densities. Data is modelled as a multivariate locally linear random process. We derive an expression for the asymptotic likelihood of a linear process segment, which allows us to formulate and optimize a mixture model via the EM algorithm. The mixture model is able to represent nonstationary (locally, ...

This paper presents a blind source separation process for convolutive mixtures of audio sources. Here undetermined condition that is few microphones than sources has been considered as a mixing model. By an expectation–maximization (EM) algorithm the separation operation is performed in the frequency domain. The T-F masking separation is made use which is a powerful approach for the separation ...

Recent progress in the theory and practice of voltammetry is surveyed and evaluated. The transformation over the last decade of the level of modelling and simulation of experiments has realised major advances such that electrochemical techniques can be fully developed and applied to real chemical problems of distinct complexity. This review focuses on the topic areas of: multistep electrochemic...

The oxidative behavior of Auranofin, 2,3,4,6-tetra-O-acetyl-1-thio-beta-D-glucopyranosato- S(triethylphosphine)gold(I), was investigated by using cyclic voltammetry (CV) in 0.1 M Bu(4)NPF(6)/CH(2)Cl(2) and 0.1 M Bu(4)NPF(4)/CH(2)Cl(2) solutions using Pt working and auxiliary electrodes and a Ag/AgCI reference. CV studies at scan rates from 50-2,000 mV/s and Auranofin concentrations between 1 an...