Molecular dynamics (MD) simulations of mixtures of the room temperature ionic liquids (ILs) 1-butyl-4-methyl imidazolium [BMIM]/dicyanoamide [DCA] and [BMIM][NO3(-)] with HNO3 have been performed utilizing the polarizable, quantum chemistry based APPLE&P(®) potential. Experimentally it has been observed that [BMIM][DCA] exhibits hypergolic behavior when mixed with HNO3 while [BMIM][NO3(-)] does...

the present investigation entails a procedure by which the surface tension and viscosity of liquids could be redicted.to this end, capillary experiments were performed for porous media by utilizing fifteen different liquids and powders. the time of capillary rise to a certain known height of each liquid in a particular powder was recorded. two artificial neural networks (anns) were designed and...

Using field-theoretic techniques, we study the solvation of salt ions in liquid mixtures, accounting for the permanent and induced dipole moments, as well as the molecular volume of the species. With no adjustable parameters, we predict solvation energies in both single-component liquids and binary liquid mixtures that are in excellent agreement with experimental data. Our study shows that the ...

The spectrum of the luminescence pulse from collapsing laser-induced bubbles in water and cryogenic liquids has been measured. For small bubbles in water the spectrum approximates that of a black-body at about 7800 K, while for bubbles whose maximum radius is greater than 1 mm the OH* molecular band at 310 nm becomes apparent, a feature which is also seen in multi-bubble sonoluminescence. The l...

BACKGROUND The valorization of biomass for chemicals and fuels requires efficient pretreatment. One effective strategy involves the pretreatment with ionic liquids which enables enzymatic saccharification of wood within a few hours under mild conditions. This pretreatment strategy is, however, limited by water and the ionic liquids are rather expensive. The scarce understanding of the involved ...

Noble gases that form clathrate hydrates when dissolved into water and restrict water molecule activity can prolong the shelf life of fruits and vegetables. Physiological and physical aspects of asparagus spears treated with mixtures of compressed (1.1MPa absolute) argon (Ar) and xenon (Xe) (2:9 in partial pressure) were compared with controls under normal preservation in modified atmosphere pa...