We report a method for synthesizing various shaped colloidal microparticles using microfluidic devices with structured elastomeric membranes. These elastomeric membranes incorporated between two-layered channels have negative relief structures, and pneumatically actuated membrane leads to confinement of fluid inside structures. Using this microfluidic system, we demonstrate synthesis of various...

Introduction. I. Nutrition of the Blood Vessel 'Wall: Review of the Literature. II. The Response of the Rabbit's Carotid Artery to Injuries. Introduction. Material and Methods. The Effect of Double Ligation. The Effects of Injection of Streptococcus viridans and of Silica. The Effects of Injection of Tubercle Bacilli and of Colloidal Cholesterol. Discussion. III. Studies on Experimental Coronar...

In this work we describe a novel and simple self-assembly process of colloidal silica beads to create a nanofluidic junction between two microchannels. The nanoporous membrane was used to induce ion concentration polarization inside the microchannel and this electrokinetic preconcentration system allowed rapid concentration of DNA samples by ~1700 times and of protein samples by ~100 times with...

Rings and split rings of sub-micrometer size are prepared by the infiltration of colloidal crystals of spherical silica particles with diameters of about 1 lm by diluted solutions of tetrachloroauric acid in butanone, followed by the evaporation of the butanone, the annealing of the samples at elevated temperatures and the removal of the silica spheres with hydrofluoric acid. X-ray photoelectro...

We report an experimental study on the drying of silica colloidal dispersions. Here we focus on surface instability occurring in a drying paste phase before crack formation which affects the final film quality. Observations at macroscopic and microscopic scales reveal the occurrence of instability, and the morphology of the film surface. Furthermore, we show that the addition of adsorbing polym...

We describe the synthesis and the physical properties of suspensions of colloidal silicon and silica rodlike particles. In addition to pure silicon and pure silica rods, we have also synthesized silicon rods with a silica shell and silica rods with a fluorescent silica layer. Pre-patterned p-type (100) silicon wafers were electrochemically etched in electrolyte solutions containing hydrogen flu...

We report observations of the optical stop band of periodic planar arrays of submicron silica spheres, and of macroporous polymers grown from these silica templates. The stop-band width and peak attenuation depend on the number of layers and on the dielectric contrast between the spheres and the interstitial regions, both of which are experimentally controlled. The results are compared to the p...

Large colloidal environmentally stable silica-coated cobalt particles were synthesized by combining the sodium borohydride reduction in aqueous solution and the Stöber method. Low size polydisperse cobalt spheres with an average size of 95 nm were synthesized by using a borohydride reduction method and were subsequently coated with a thin layer of silica by means of hydrolysis and condensation ...

The efficient synthesis of all-acrylic, film-forming, core-shell colloidal nanocomposite particles via in situ aqueous emulsion copolymerization of methyl methacrylate with n-butyl acrylate in the presence of a glycerol-functionalized ultrafine silica sol using a cationic azo initiator at 60 °C is reported. It is shown that relatively monodisperse nanocomposite particles can be produced with ty...

Here we report that silver nanoparticle necklaces can be readily formed by treatment of colloidal silica with ammoniacal silver complex solution followed by washing, deposition and ageing. We investigate the morphology of the produced materials and elucidate the key variables that influence this promising new approach to one-dimensional nanostructuring.