We present the results of a comprehensive photoluminescence study of defect centres in single SiO2 nanoparticles. We show that the photo-physical properties of the luminescent centres strongly resemble those of single dye molecules. However, these properties exhibit a large variability from particle to particle due to the different local chemical environment around each centre of each particle....

A reaction set of possible mineral weathering reactions is proposed to explain observed cation and silica export for the Emerald Lake watershed, a small Sierra Nevada, California catchment. The reaction set was calculated through a stoichiometric mole-balance method, using a multiyear record of stream flow and snowpack chemical analyses and site-specific mineral compositions. Reaction-set calcu...

Matched-Molecular Pair (MMP) analysis has recently emerged as a data analysis technique in medicinal chemistry. It quickly gained scientific momentum because it tackles key questions in lead optimization. In contrast to classical global QSAR models that attempt to predict the absolute numbers of ADME (absorption, distribution, metabolism, excretion) and toxicological properties, MMP analyses pr...

Spatial properties of field soils vary in a complex manner. Especially in arid and semiarid areas, this variability affects plant quality and crop production. An experimental field plot was extensively sampled regarding soil water (378 gravimetrical samples), soil chemical content (314 samples), and crop yield and chemical content (26 samples) at the Cherfech agricultural field research station...

A database of approximately 20,000 chemical exposures has been constructed in close co-operation between the School of Public Health of the University of North Carolina at Chapel Hill and the Department of Air Pollution of the Wageningen Agricultural University. A special feature of this database is that only multiple measurements of exposure from the same workers were included. This enabled es...

the aim of this study was to determine the extent of metal pollutions and the identification of their major sources in the vicinity of the sangan iron mine occurring in ne iran. soil samples were collected from the vicinity of the mine site and analyzed for heavy metals. in addition, the chemical speciation of these metals was investigated by means of the sequential extraction procedure. the st...

Variability in plant chemistry has long been believed to suppress populations of insect herbivores by constraining herbivore resource selection behavior in ways that make herbivores more vulnerable to predation. The focus on behavior, however, overlooks the pervasive physiological effects of plant variability on herbivores. Here we propose the plant variability-gut acclimation hypothesis, which...

Trenholm for their supportive efforts throughout this learning experience. I give special thanks to Dr. Shober, my committee chair, for her encouragement, direction and commitment. I am also appreciative to Gitta Shurberg for her assistance in the field as well as laboratory. Abstract. Urban soils have highly variable chemical, physical, and biological properties compared to undisturbed natural...

[1] Transport of boundary layer air to the free troposphere by cyclones during NASA’s Transport and Chemical Evolution over the Pacific (TRACE-P) experiment is investigated. Airstreams responsible for boundary layer venting are diagnosed using results from a high-resolution meteorological model (MM5) together with in situ and remotely sensed chemical data. Hourly wind data from the MM5 are used...

OBJECTIVES Workers in many industries are exposed to endotoxins, which may cause adverse health effects. In exposure assessment, information about exposure variability is essential. However, variability in exposure has rarely been investigated for biological agents and more specifically for endotoxin. Therefore, variance components and determinants of exposure were studied in a large database w...