atom transfer radical polymerization (atrp) of styrene was carried out at 105°c and a monte carlo simulation was employed to model the system. the variations of monomer conversion, the initiator concentration, average molecular weight, and molecular weight distribution were evaluated as the reaction proceeded. according to the results obtained, for similar reaction time, monomer conversion is h...

Re-polymerization reactions are a commonly reported issue on the way to higher recovery of monomers from lignin. The reactivity obtained lignin depolymerization and their contribution re-polymerization in supercritical water (SCW) was investigated. Sulfonated Kraft (SKL) used along with four monomers: vanillin, vanillic acid, vanillyl alcohol acetovanillone. Indulin also employed as reference u...

A novel supramolecular self-assembly nanostructure of porous helical nanoribbons (PHNRs) was developed. PHNRs from oligoaniline derivatives were fabricated through the chemical oxidation aniline in an i-propanol/water mixture as mediated by β-cyclodextrin (β-CD). The role β-CD considered vital modulation addition time point and molar ratio β-CD/aniline. In addition, at early stage polymerizatio...

Nanocomposite of polyaniline (PAn) containing nanometre size Sb2O3 was prepared in aqueous media in situ chemical oxidative polymerization method at room temperature in the presence of hydroxypropylcellulose (HPC) as a surfactant. The ability of product to removal of lead ions from aqueous solution was studied. The chemical structure and morphology were studied by fourier transform infrared (FT...

Polymers of hydrogen cyanide and their hydrolysis products constitute a plausible, but still poorly understood proposal for early prebiotic chemistry on Earth. HCN polymers are generated by the interplay of more than a dozen distinctive reaction mechanisms and form a highly complex mixture. Here we use a computational model based on graph grammars as a means of exploring the chemical spaces of ...