Highly ordered TiO2 nanotube arrays (TiO2-NTAs), with a uniform tube size on titanium substrate, were obtained by means of reoxidation and annealing. A composite structure, CdSe quantum dots@TiO2 nanotube arrays (CdSe QDs@TiO2-NTAs), was fabricated by assembling CdSe quantum dots into TiO2-NTAs via cyclic voltammetry electrochemical deposition. The X-ray diffractometer (XRD), field-emission sca...

A transferable force field for the PbSe-CdSe solid system using the partially charged rigid ion model has been successfully developed and was used to study the cation exchange in PbSe-CdSe heteronanocrystals [A. O. Yalcin et al., "Atomic resolution monitoring of cation exchange in CdSe-PbSe heteronanocrystals during epitaxial solid-solid-vapor growth," Nano Lett. 14, 3661-3667 (2014)]. In this ...

Reaction of 3-aminopropylsilyl-modified ZnO microrods with trioctylphosphineoxide-coated CdSe/CdS core/shell nanocrystals in THF produces rod-shaped nanoparticle clusters that show directional photoemission that can be tuned with the size of the CdSe nanocrystals. The observed waveguiding effect of these microstructures is due to total internal reflection of light at the cluster-air interface.

Flower-like CdSe architectures composed of ultrathin nanosheets were prepared via a facile solvothermal method. A relationship was established between the solvothermal temperature and the product structure, and thus the photocatalytic activity. When compared with well-studied CdSe quantum dots, the ultrathin nanosheet assemblies exhibited a better photocatalytic H2 evolution activity under visi...

The high pressure band structure, density of states, metallization, structural phase transition and superconductivity of cubic zinc blende type zinc selenide (ZnSe) and cadmium selenide (CdSe) are investigated using the full potential linear muffin-tin orbital (FP-LMTO) method. The ground state properties and band gap values are compared with the experimental results. The equilibrium lattice co...

The small thiol β-mercaptoethanol (BME) has been used as an anti-blinking reagent for CdSe/ZnS quantum dots (QDs), although its effects on QD photoluminescence are complex. It acts as an antioxidant as well as a hole scavenger on both CdSe and CdTe, which leads to changes in emission intensity and lifetime that vary qualitatively according to BME concentration, time of incubation, and pH of the...

We report detailed studies of the photoluminescence ~PL! properties of CdSe quantum dots ~QDs! grown on ZnSe and Zn0.97Be0.03Se by molecular-beam epitaxy. We performed steady-state and time-resolved PL measurements and observed that nonradiative processes dominate at room temperature ~RT! in the CdSe/Zn0.97Be0.03Se QD structures while these nonradiative processes do not dominate in the CdSe/ZnS...

• Exploring the role of surfactants on nanoscale metal oxide synthesis. A nonionic surfactant (Polyvinyl pyrrolidone) based TiO 2 effectively wrap CdSe. Cationic and anionic deform CdSe host or result in agglomerated 2. CdSe/TiO composite results 8 times enhancement H production than Benchmarking shell coated exhibits 23.1 h −1 .g cat hydrogen gas. The present work demonstrates effect cationic,...

Quantum dots with emission in the spectral region from 525 to 535 nm are of special interest for their application in green LEDs and white-light generation, where CdSe/ZnS core-shell structured nanocrystals (NCs) are among promising candidates. In this study, triple-ligand system (trioctylphosphine oxide–oleic acid–oleylamine) was designed to improve the stability of CdSe NCs during the early r...

Quantum dots (QDs), semiconducting materials have potential applications in the field of electronic and biomedical applications including cancer therapy. In present study, cadmium selenide (CdSe) QDs were synthesized by chemical method. Octadecene was used as non-coordinating solvent which facilitated the formation of colloidal solutions of nanoparticles. CdSe QDs were characterized by UV-vis s...