background: the widespread use of toluene and its consequent adverse effects on health and specially its chronic effects on the central nervous system has resulted in many studies being carried out on the methods that can control and reduce toluene vapors in the airflow. the objective of this study is to assess the effectiveness of the catalytic ozonation process in the removal of toluene from ...

we have used tungestophosphoric acid to catalyze oxidative amidation reaction from benzyl alcohols and methylarens with hydrochloride salts of amines. to achieve this purpose, modified magnetic nanoparticles (γ-fe2o3@sio2@h3pw12o40) were applied as catalyst and tbhp as external oxidant. after optimizing, different derivates of benzamides were synthesized in good yields. also, the result of two ...

introduction: dye removal from industrial wastewater has been considered as one of the most environmental issues. recently, new methods of treatment such as catalytic ozonation have been used to increase dye removal efficiency. so, the efficiency of catalytic ozonation by copper coated zeolite as a catalyst in the removal of reactive red 198 was investigated. materials & methods: in order to re...

a simple, rapid and sensitive spectrophotometric method has been proposed for the determinationof vanadium (iv). the method is based on the catalytic effect of v (iv) on the oxidation of alkali blue bypotassium bromate at ph 4. the rate of decrease in the absorbance of alkali blue (at 572 nm) wasproportional to the concentration of v (iv) in the range of 100-6000 ng ml-1. the detection limit wa...

the waste tyres represent a source of energy and valuable hydrocarbon products. waste tyres were pyrolysed catalytically in a batch reactor under atmospheric pressure. the effects of basic catalysts (mgo and caco3) were studied on the pyrolysis products. the distribution ratio of gas, liquid and char with mgo and caco3 were 24.4:39.8:35.8 wt % and 32.5:32.2:35.2 wt % respectively at 350°c for 2...

a kinetic-spectrophotometric procedure is reported for determination of trace amounts of ag(i). this method is based on catalytic effect of silver ion on the oxidation of congo red by potassium peroxodisulphate at ph=3.4 and 30 oc in the presence of 1,10-phenanthroline as an activator. the reaction was followed spectrophotometrically by measuring the rate of change in absorbance of congo red at...

a catalytic-kinetic method for the determination of selenium is proposed. alizarin navy blue is reduced by sodium sulfide to from a colorless product. the reaction is accelerated by trace amounts of se (iv), and can be followed by measuring the decrease in absorbance of the dye at 620nm and 30 °c by the fixed time method. selenium can be determined in the range of 0.004 — 0.12 1.1g.m1-1 . ...

The unfolding mechanism of the 13 alpha-helices in the catalytic domain of Aspergillus awamori var. X100 glucoamylase was investigated by 200 ps molecular dynamics simulations in explicit water with temperature jump technique. Rather than a simultaneous event, the unfolding of these 13 alpha-helices followed a random ordered mechanism as alpha8-->alpha1-->alpha11-->alpha7-->alpha10-->alpha3-->a...

The ever-improving time and space resolution and molecular detection sensitivity of fluorescence microscopy offer unique opportunities to deepen our insights into the function of chemical and biological catalysts. Because single-molecule microscopy allows for counting the turnover events one by one, one can map the distribution of the catalytic activities of different sites in solid heterogeneo...

In 1981 Pecoraro and Chianelli reported a complete study of catalytic behavior of transition metal sulfides catalysts in hydrodesulfurization (HDS) of dibenzothiophene (DBT) [1], in which was found a periodic tendency of the metallic sulfides activity, where ruthenium sulfide showed the highest HDS activity. These results were corroborated later by Raje et al. [2] and Liaw et al. [3], further s...