نتایج جستجو برای: carboxylic acid functionalized carbon nanotubes covalent interaction

تعداد نتایج: 1554167  

2014
Antonello Di Crescenzo Valeria Ettorre Antonella Fontana

Carbon nanotubes (CNTs) have been proposed and actively explored as multipurpose innovative nanoscaffolds for applications in fields such as material science, drug delivery and diagnostic applications. Their versatile physicochemical features are nonetheless limited by their scarce solubilization in both aqueous and organic solvents. In order to overcome this drawback CNTs can be easily non-cov...

2015
Tsuyohiko Fujigaya Naotoshi Nakashima

Carbon nanotubes (CNTs) have been recognized as a promising material in a wide range of applications from biotechnology to energy-related devices. However, the poor solubility in aqueous and organic solvents hindered the applications of CNTs. As studies have progressed, the methodology for CNT dispersion was established. In this methodology, the key issue is to covalently or non-covalently func...

Journal: :Journal of the American Chemical Society 2007
Adam C Whalley Michael L Steigerwald Xuefeng Guo Colin Nuckolls

This manuscript compares the conductance when molecules connecting single-walled carbon nanotubes (SWNTs) change their states of conjugation. We use electrodes made by excising a nanoscale section from an individual SWNT, having shown previously that this is a general method to wire a small number (<10) of molecules into electrical circuits (Figure 1A).1-3 These SWNT molecular devices can be ma...

2010
Muataz Ali Atieh Omer Yehya Bakather Bassam Al-Tawbini Alaadin A. Bukhari Faraj Ahmad Abuilaiwi Mohamed B. Fettouhi

The adsorption mechanism of the removal of lead from water by using carboxylic functional group (COOH) functionalized on the surface of carbon nanotubes was investigated. Four independent variables including pH, CNTs dosage, contact time, and agitation speed were carried out to determine the influence of these parameters on the adsorption capacity of the lead from water. The morphology of the s...

Journal: :Physical review letters 2004
J A Aström A V Krasheninnikov K Nordlund

We employ a theoretical model to calculate mechanical characteristics of macroscopic mats and fibers of single-walled carbon nanotubes. We further investigate irradiation-induced covalent bonds between nanotubes and their effects on the tensile strength of nanotube mats and fibers. We show that the stiffness and strength of the mats can be increased at least by an order of magnitude, and thus s...

2009
Jun Jin Zhengping Dong Jianguo He Rong Li Jiantai Ma

Novel covalent porphyrin and its complexes (Co(2+), Zn(2+)) functionalized multi-walled carbon nanotubes (MWNTs) have been successfully synthesized by the reaction of the carboxyl on the surface of MWNTs which was synthesized to use carbon radicals generated by the thermal decomposition of azodiisobutyronitrile (AIBN) with 5-p-hydroxyphenyl-10,15,20-triphenyl-porphyrin and its complexes (Co(2+)...

Journal: :Chemical communications 2016
Antoine Maurin Marc Robert

The covalent grafting of an Fe porphyrin on carbon nanotubes led to efficient electroreduction of CO2 into CO in water (pH 7.3). CO was obtained with high selectivity and turnover at 0.5 V overpotential. The grafting strategy may be further extended to various conductive and semi-conductive surfaces.

Journal: :Nanotechnology 2008
Ting Zhang Syed Mubeen Nosang V Myung Marc A Deshusses

The development of carbon nanotube-(CNTs-)based gas sensors and sensor arrays has attracted intensive research interest in the last several years because of their potential for the selective and rapid detection of various gaseous species by novel nanostructures integrated in miniature and low-power consuming electronics. Chemiresistors and chemical field effect transistors are probably the most...

Journal: :Journal of the American Chemical Society 2011
Fei Wang Timothy M Swager

A diverse array of multiwalled carbon nanotube (MWCNT) sensory materials have been synthesized and used to create sensors capable of identifying volatile organic compounds (VOCs) on the basis of their functional groups. Functionalized MWCNTs with a series of cross-sensitive recognition groups were successfully synthesized via zwitterionic and post-transformation synthetic procedures. The incorp...

Journal: :Nature nanotechnology 2007
Raymond W Friddle Melburne C Lemieux Giancarlo Cicero Alexander B Artyukhin Vladimir V Tsukruk Jeffrey C Grossman Giulia Galli Aleksandr Noy

Carbon nanotubes display a consummate blend of materials properties that affect applications ranging from nanoelectronic circuits and biosensors to field emitters and membranes. These applications use the non-covalent interactions between the nanotubes and chemical functionalities, often involving a few molecules at a time. Despite their wide use, we still lack a fundamental understanding and m...

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