The challenge in preparation of ionic liquids containing a strong alkaline anion is to identify a suitable cation which can tolerate the harsh conditions induced by the anion. In this study, a commercial quaternary ammonium compound (quat) benzalkonium [ADBA] (alkyldimethylbenzylammonium) was used as a cation in the synthesis of different alkaline ionic liquids. In fact, the precursor, benzalko...

The present work describes the development and application of a carbon paste electrode modified by treated-Pennisetum setosum for the determination of lead(II) by anodic stripping differential pulse voltammetry. Most experiments were performed using the preconcentration/voltammetry/regeneration scheme. The resulting modified electrode offers a preferential uptake of lead(II) from solutions. Ope...

The electrochemical and electromechanical properties of actuators based on an ionic fluoropolymer (NafionTM) and non-ionic fluoropolymer (poly(vinylidene fluoride-co-hexafluoropropylene) [PVdF(HFP)]) gel fabricated using a single-walled carbon nanotube (SWCNT) – an ionic liquid (IL) gel electrode, were compared with those of actuators based on a non-ionic fluoropolymer (PVdF(HFP)). The ionic co...

Article history: Received 13 January 2014 Accepted 9 February 2014 Available online 13 February 2014 Two major issues of conventional supercapacitors, composed of a separator, two electrodes, and liquid electrolyte, are their low package energy density and the leakage of the liquid electrolyte. Therefore, great efforts have been dedicated in development of allsolid-state supercapacitors with hi...

A novel multifunctional material has been designed to provide excellent mechanical properties while possessing a high electrochemical surface area suitable for electrochemical energy storage: structural carbon fiber fabrics are embedded in a continuous network of carbon aerogel (CAG) to form a coherent but porous monolith. The CAG-modification process was found to be scalable and to be compatib...

A laser photochemical process is introduced to realize superhydrophobic conducting carbon coatings with broccoli-type hierarchical morphology for use as a metal-free counter electrode in a dye sensitized solar cell. The process involves pulsed excimer laser irradiation of a thin layer of liquid haloaromatic organic solvent o-dichlorobenzene (DCB). The coating reflects a carbon nanoparticle-self...

Due to the protection of ionic liquid polymer thin film, the long-term operation stability of carbon nanotube-supported platinum nanoparticles for methanol electrooxidation has been improved.