A tendency to an increase in migration times was observed when different water-soluble vitamins were analysed repeatedly in pharmaceutical preparations by capillary electrophoresis. In order to better understand the origin of this effect, the influence of the vitamins and the excipients, such as cellulose derivatives, was investigated. These studies indicated that the increase in analyte migrat...

The rheological properties of capillary suspensions, suspensions with small amounts of an added immiscible fluid, are dramatically altered with the addition of the secondary fluid. We investigate a capillary suspension to determine how the network ages and restructures at rest and under applied external shear deformation. The present work uses calcium carbonate suspended in silicone oil (11 % s...

In a previous study, we established that the attraction between electrically charged particles attached to a water/tetradecane interface is stronger than predicted on the basis of the gravity-induced lateral capillary force. Here, our goal is to explain this effect. The investigated particles are hydrophobized glass spheres of radii between 240 and 320 microm. Their weight is large enough to de...

To take capillary effect into account, a series of primary drainage experiments of water by a sample oil fluid have been studied. The experiments performed under different low flow rates on a horizontal glass type micromodel as a model of porous media. Based on conventional macroscopic flow equations, the relative permeabilities and capillary pressure are determined by parameter estimation tech...

[1] This work presents a series of numerical modeling studies that investigate the hydrogeologic conditions required to form capillary barriers and the effect that capillary barriers have on fluid flow and tracer transport processes in the unsaturated fractured rock of Yucca Mountain, Nevada, a potential site for storing high-level radioactive waste. The modeling approach is based on a dual-con...

The streaming potentials generated by the flow of both liquid and gas through either a Pyrex capillary tube or else an unconsolidated Pyrex porous medium were investigated. This mixture of distilled water plus nitrogen gas simulated wet steam but allowed experiments to be run at room temperature. Single-phase flow of distilled water alone resulted in a constant voltage-to-pressure drop ratio, W...

Several methods are compared for the detection of moving capillary fronts in spontaneous imbibition experiments where water invades dry porous rocks. These methods are: (i) the continuous monitoring of the mass increase during imbibition, (ii) the imaging of the water front motion using X-ray CT scanning, (iii) the use of ultrasonic measurements allowing the detection of velocity, amplitude and...

This study was designed to examine the potential effect(s) of dietary supplementation with L-arginine on the renal microcirculation of female Munich-Wistar rats with ablation of 60 to 70% of total renal mass. All rats were fed a standard rat chow containing 22.8% protein (1.42% L-arginine). Groups 1 (N = 6) and 3 (N = 7) drank tap water and had micropuncture studies after 5 to 6 or 15 to 16 wk,...

Both the hardening process and formation of microstructure of concrete are significantly influenced by the curing condition. The capillary absorption of concrete is closely related to the structure and distribution of the pores within the material. This paper presents an experimental study on the influence of four curing conditions, i.e., standard curing, natural curing, water curing, and seale...

Capillary porosity percolation in a hydrating cement paste has a large influence on transport properties and durability. Percolation can be examined using low-temperature calorimetry and using microstructure models. In this paper, the two approaches are compared for cement pastes with different water-to-cement ratios and exposed to various curing conditions. The influence of sealed curing is se...