The photocatalytic degradation of Evans Blue has been studied under visible light in the presence of N-doped ZnO as a photocatalyst. N-doped ZnO was prepared by the solvent free method. The photocatalytic activity of ZnO and N-doped ZnO was compared by investigating the photodegradation of Evans Blue dye under visible light. The effect of different parameters like pH, concentration of the Dye, ...

Subnanosecond lifetime measurements using picosecond pulses from a mode locked Nd3+/glass laser together with conventional absorption and fluorescence yield methods have been used to study the photophysics of fluorescein and three of its halogenated derivatives (eosin, erythrosin, and rose bengal) in aqueous and simple alcoholic solvents. For each of the dye molecules absorption and fluorescenc...

We have calculated the reorganisation energy for the intramolecular electron transfer between the reduced type 1 copper site and the peroxy intermediate of the trinuclear cluster in the multicopper oxidase CueO. The calculations are performed at the combined quantum mechanics and molecular mechanics (QM/MM) level, based on molecular dynamics simulations with tailored potentials for the two copp...

We have calculated the reorganization energy for the intramolecular electron transfer between the reduced type 1 copper site and the peroxy intermediate of the trinuclear cluster in the multicopper oxidase CueO. The calculations are performed at the combined quantum mechanics and molecular mechanics (QM/MM) level, based on molecular dynamics simulations with tailored potentials for the two copp...

The demonstration that copper is transported in the serum (1) makes available a means of studying copper metabolism and gives rise to the necessity of having a simple and accurate method which can be applied to the measurement of a large number of samples. The purpose of this paper is to present such a method. Sodium diethyldithiocarbamate has been found t,o be a sat’isfactory and sensitive rea...

Surface-enhanced Raman scattering ~SERS! spectroelectrochemical investigations have been carried out in real time on the electrodeposition of copper from sulfuric acid solutions. Sulfate spectra were observed during copper deposition, but not on a copper surface at the same potential in the absence of copper ions in solution. This indicated that sulfate adsorption is a transient process associa...

A series of bis(σ-B-H) complexes of copper(i) have been prepared by displacement of arene solvent from a β-diketiminate copper(i) complex by four-coordinate boranes, H3B-L (L = NMe3, lutidine). In the presence of the same copper arene complex, the secondary amine-borane H3B-NMe2H undergoes dehydrogenation. We provide evidence for formation of a heterogengous catalyst from decomposition of the s...

a simple, rapid and sensitive method has been developed for determination of trances of tellurium (vi) (0.096-1.250 mg/ml) based on its catalytic effect on the reduction reaction of toluidine blue by sulfide ion at ph 4. the reaction is monitored spectrophotometrically by measuring the decrease in absorbance of the dyestuff at 628 nm by the fixed time method. the detection limit is 80 ng/ml and...

Purpose: To evaluate protein hydrolysates and membrane ultrafiltration fractions of blue-spotted stingray for metal chelating and radical scavenging activities, as well as protection against oxidative protein damage. Methods: Stingray protein isolates were hydrolysed with alcalase, papain and trypsin for 3 h. Alcalase hydrolysate was fractionated by membrane ultrafiltration to yield < 3, 3 10 a...