Terahertz pulses are applied as an all-optical bias to ferroelectric thin-film BiFeO3 while monitoring the time-dependent ferroelectric polarization through its nonlinear optical response. Modulations in the intensity of the second harmonic light generated by the film correspond to on-off ratios of 220× gateable on femtosecond timescales. Polarization modulations comparable to the built-in stat...

A preferred piezoelectric ceramic material is a BiFeO3—PbZrO3—PbTiO3 ternary solid solution wherein proportions of the constituent perovskite metal oxides are selected so that the material exhibits relatively high Curie temperatures above 380° C. and useful piezoelectric properties. Disciplines Ceramic Materials This patent is available at Iowa State University Digital Repository: http://lib.dr...

BiFeO3–CoFe2O4 nanocomposite thin films R. Muralidharan, N. Dix, V. Skumryev, M. Varela, F. Sánchez, and J. Fontcuberta Institut de Ciència de Materials de Barcelona-CSIC, Campus UAB, Bellaterra 08193, Spain Institut Català de Recerca i Estudis Avançats (ICREA), Barcelona, Spain Departament de Física Aplicada i Òptica and Institut de Nanociència i Nanotecnologia (IN2UB), Universitat de Barcelon...

Ultrafast spectroscopy can provide unique tools to study and control electronic and structural dynamics on a femtosecond time scale. Here we study, the yet little explored multiferroic material, BaTiO3-BiFeO3 (BTO-BFO), that has demonstrated enhanced magnetic properties, a higher DC resistance in comparison to BFO, and improved magnetoelectric coupling. Our studies include ultrafast time resolv...

Monocrystalline mesoporous BiFeO3 crystals were obtained via a multi-step single-crystal to single-crystal transformation of a coordination polymer, Bi[Fe(CN)6]·4H2O. This unique transformation process significantly decreased the crystallization temperature of perovskite oxide without losing high crystallinity.

Nucleoside triphosphates (NTPs) at 4-10 microM concentrations were found to inhibit the rates of collagen-induced in vitro mineralization and ion exchange reactions. The sequential removal of the terminal phosphate groups caused a step-wise decrease in their inhibitory potency. The results suggest that NTPs inhibit the rates of ion uptake and exchange reactions at concentrations much lower than...

A drastic change in the conductivity of strained BiFeO3 (BFO) films is observed after illuminating them with above-band gap light. This has been termed as persistent photoconductivity. The enhanced conductivity decays exponentially with time. A trapping character of the sub-band levels and their subsequent gradual emptying is proposed as a possible mechanism.

BiFeO3 (BFO) multiferroic oxide has a complex phase diagram that can be mapped by using appropriately substrate-induced strain in epitaxial films. By using Raman spectroscopy, we conclusively show that films of the so-called supertetragonal T-BFO phase, stabilized under compressive strain, display a reversible temperature-induced phase transition at about 100 °C, and thus close to room temperat...

substituted BiFeO3 epitaxial thin films at morphotropic phase boundaries Daisuke Kan, Ching-Jung Cheng, Valanoor Nagarajan, and Ichiro Takeuchi Department of Materials Science and Engineering, University of Maryland, College Park, Maryland 20742, USA Institute for Chemical Research, Kyoto University, Gokasyo Uji, Kyoto 611-0011, Japan School of Materials Science and Engineering, University of N...