Suzuki-Miyaura cross-couplings of arenediazonium salts with arylboronic acids catalyzed by highly active aluminium hydroxide-supported palladium nanoparticles catalyst have been investigated for the first time. The reactions are performed at 25 °C in MeOH without any base and ligand to afford biaryls in good to excellent yields under non-anhydrous and non-degassed conditions.

Saliva has a buffer capacity which neutralizes acids in the mouth. The buffer capacity of human saliva is regulated by 3 buffer systems: the carbonic acid/bicarbonate system, the phosphate system, and the proteins. In nonstimulated saliva, the concentration of inorganic phosphate is rather high, while the concentration of carbonic acid/bicarbonate system is low. Carbonic acid/bicarbonate system...

A mechanistic study of arylations of aliphatic alcohols and hydroxide with diaryliodonium salts, to give alkyl aryl ethers and diaryl ethers, has been performed using experimental techniques and DFT calculations. Aryne intermediates have been trapped, and additives to avoid by-product formation originating from arynes have been found. An alcohol oxidation pathway was observed in parallel to ary...

Published researches about the pretreatment of exit wastewater from desalination units are rare. Nowadays, lake of potable water, development of industries and population growth, extend desalination units. Although desalination units have been grown up, but exit brine stream is usually drained into the sea ecosystem [1-4]. Moreover, annually a large quantity of concentrated brine is discharged ...

In this work attempts were made to evaluate K+-SDS and hydrocolloid polymer-SDS interactions in flocculation of megestrol acetate dispersions to enhancetheir stability as a part of suspension formulation. Different dispersions of micronized megestrol acetate and SDS were prepared. KCl and KH2PO4 and their corresponding sodium salts were added to the dispersions and the preparations were evaluat...

The reactivity of sodium borohydride in the presence of other species has been examined by adiabatic calorimetry. In combination with water, sodium borohydride exhibits an exotherm at room temperature accompanied by generation of gas (presumed to be hydrogen). Addition of potassium hydroxide to a sodium borohydride-water mixture is found to stabilize the solution and require a higher temperatur...

0016-2361/$ see front matter 2011 Elsevier Ltd. A doi:10.1016/j.fuel.2011.03.042 Abbreviations: CFME, chicken fat methyl esters; American society of testing and materials; KOH, p sodium hydroxide; KOMe, potassium methoxide; NaO ⇑ Corresponding author at: Department of Automo Kocaeli University, 41380 Kocaeli, Turkey Tel.: +90 3032203. E-mail addresses: [email protected], Canakci). In t...

Hydroxide anions are identified as catalytically active species for the isomerization of d -glucose to -fructose over low soluble basic salts. The highest selectivity was obtained catalysis by MgCO 3 .

In a recent study (1) it was shown that cystine could be decomposed by boiling distilled water with the formation of cysteine, hydrogen sulfide, and elementary sulfur. The decomposition of cysteine under similar conditions should aid in a clearer explanation of the mechanisms involved in the breakdown of these two amino acids. The action of alkaline reagents on cysteine and its derivatives has ...

In a recent study (1) it was shown that cystine could be decomposed by boiling distilled water with the formation of cysteine, hydrogen sulfide, and elementary sulfur. The decomposition of cysteine under similar conditions should aid in a clearer explanation of the mechanisms involved in the breakdown of these two amino acids. The action of alkaline reagents on cysteine and its derivatives has ...