In the title complex, [Cu(C13H11N2O)(N3)], the Cu(II) cation is four-coordinated by an N2O donor set of the tridentate Schiff base ligand and by the terminal N atom of the azide anion, forming a slightly distorted square-planar configuration.

Conjugated Schiff base macrocycles with wide bores and conformational flexibility bind organic cations in their interiors, and can be used to assemble larger supramolecular structures.

The title compound, C(27)H(19)BrN(4)O, is a mono-anil Schiff base ligand. Three intra-molecular O-H⋯N and N-H⋯N hydrogen bonds involving the hydr-oxy and amino groups generate S(6) and S(5) ring motifs, respectively. In the crystal structure, weak inter-molecular N-H⋯O and C-H⋯O hydrogen bonds together with π-π inter-actions [centroid-centroid distances = 3.628 (3)-3.729 (3) Å] link neighboring...

In the title linear homo-trinuclear complex, [Cd3(C19H18Cl2N2O2)2(C2H3O2)2], the central Cd(II) atom is located on a centre of inversion and has a distorted octa-hedral coordination geometry formed by four O atoms from two bidentate/tetra-dentate Schiff base ligands and two O atoms from two bridging acetate ligands. The coordination geometry of the terminal Cd(II) atom is square-pyramidal with ...

Schiff bases exhibited sensor activity via cyclic voltammetry, colorimetry, and UV-vis study at room temperature. The probes could be employed as a low-cost, ultrasensitive chemo-sensor to detect Cu 2+ Zn in solutions.

Three bidentate Schiff bases having nitrogen and sulphur donor sequences were prepared by condensing S-benzyldithiocarbazate (NH(2)NHCS(2)CH(2)C(6)H(5)) with heterocyclic aldehydes. The reaction of diphenyltin dichloride with Schiff bases leads to the formation of a new series of organotin(IV) complexes. An attempt has been made to prove their structures on the basis of elemental analyses, cond...

Phenolic Schiff bases are known as powerful antioxidants. To select the electronic, 2D and 3D descriptors responsible for the free radical scavenging ability of a series of 30 phenolic Schiff bases, a set of molecular descriptors were calculated by using B3P86 (Becke's three parameter hybrid functional with Perdew 86 correlation functional) combined with 6-31 + G(d,p) basis set (i.e., at the B3...

A number of thiazole derived tridentate Schiff-bases (LH) and its metal chelates of the type [M(L)(2)X] where M=Ni(II), Cu(II) and Zn(II), L=substituted salicylaldehyde (5-H, 5-CH(3), 5-OCH(3), 5-NO(2) and 5-Cl) and X=CI have been synthesized and characterized with the help of elemental analyses, conductivity measurements, magnetic moments, UV-Vis, IR and NMR spectral data. An octahedral struct...

The Schiff bases HL(1-3) have been prepared by the reaction of 5-bromothiophene-2-carboxaldehyde with 4-amino-5-mercapto-3-methyl/propyl/isopropyl-s-triazole, respectively. Organosilicon(IV) and organotin(IV) complexes of formulae (CH(3))(2)MCl(L(1-3)), (CH(3))(2)M(L(1-3))(2) were synthesized from the reaction of (CH(3))(2)MCl(2) and the Schiff bases in 1 : 1 and 1 : 2 molar ratio, where M = Si...

The copper-catalyzed [3+2] azide-alkyne cycloaddition and the Staudinger ligation are readily applicable and highly efficient for the immobilization of cobalt Schiff base complexes onto polystyrene resins. Stepwise synthesis of polymer-bound Schiff bases followed by their subsequent complexation with metal ions were successfully carried out. Direct covalent attachment of preformed homogeneous c...