the reaction of ch₃nh₂ with o₂ on the singlet potential energy surfaces (pes) was carried out using the b3lyp, ccsd(t) and g3b3 theoretical approaches along with 6-311++g(3df,3pd) basis set. the suggested mechanism for the title reaction consists of one pre-reactive complex. from the pre-reactive complex, nine types of products, ch2nh+h2o2, ch3nh+ooh, nh2cho+h2o, ch2nho+h2o, nh3+hcooh, ch2nh+h2...

In the present study, the ability of different indices to quantify the coupling degree between a vegetated surface and the atmospheric boundary layer is tested. For this purpose, a one-and-a-half dimensional atmospheric boundary layer model, including a high resolved vegetation canopy, was applied (HIRVAC) and indices, such as the decoupling factor , as well as other measures derived from mode...

Scattering and absorption by aerosol in anthropogenically perturbed air masses over Europe has been measured using instrumentation flown on the UK’s BAe-146-301 large Atmospheric Research Aircraft (ARA) operated by the Facility for Airborne Atmospheric Measurements (FAAM) on 14 flights during the EUCAARI-LONGREX campaign in May 2008. The geographical and temporal variations of the derived short...

The link between atmospheric CO(2) levels and global warming is an axiom of current public policy, and is well supported by physicochemical experiments, by comparative planetary climatology and by geochemical modelling. Geological tests of this idea seek to compare proxies of past atmospheric CO(2) with other proxies of palaeotemperature. For at least the past 300 Myr, there is a remarkably hig...

Sustainable urbanization is a challenge to human beings in the modern era of technology. Cities all over the world are facing several problems due to urbanization and industrialization. Urban problems could be assessed through development of indices of urban sustainability on the basis of its three dimensions: environment, economics and social. The present study was conducted to identify indica...

We propose a modified time lag random matrix theory in order to study time-lag cross correlations in multiple time series. We apply the method to 48 world indices, one for each of 48 different countries. We find long-range power-law cross correlations in the absolute values of returns that quantify risk, and find that they decay much more slowly than cross correlations between the returns. The ...

Distributions of ellipsoids are often used to simulate the optical properties of non-ellipsoidal atmospheric particles, such as dust. In this work, the applicability of ellipsoids for retrieving the refractive index of dust-like target model particles from scattering data is investigated. This is a pure modeling study, in which stereogrammetrically retrieved model dust shapes are used as target...

Future changes in meridional sea surface temperature (SST) gradients in the tropical Atlantic could influence Amazon dry-season precipitation by shifting the patterns of moisture convergence and vertical motion. Unlike for the El Niño-Southern Oscillation, there are no standard indices for quantifying this gradient. Here we describe a method for identifying the SST gradient that is most closely...

A growing number of studies have focused on evaluating vegetation indices in terms of their sensitivity to vegetation biophysical parameters as well as to external factors affecting canopy reflectance. In this context, leaf and canopy radiative transfer models have provided a basis for understanding the behaviour of such indices, particularly their resistance to external perturbing effects rela...