a simple and efficient one-pot, three-component strecker reaction of protected amino acids, aromatic aldehydes, and trimethylsilyl cyanide has been developed for the synthesis of chiral α-amino nitriles. the reaction was carried out in the presence of catalytic amount of phosphotungstic acid (h3[p(w3o10)4]) as an environmentally friendly catalyst.

The sp3 C–H acetoxylation at the β-position of α,α-disubstituted α-amino acids proceeds smoothly under palladium catalysis in presence PhI(OAc)2. This reaction provides a straightforward synthetic route to non-natural β-acetoxy-α-amino acids. α-aminocyclopropanecarboxylic acid takes place via ring-opening selectively afford an acyclic γ-acetoxy-α,β-unsaturated amino acid.

the present study conducted to investigate the effect of energy sources and levels on performance and breast meat amino acids profile in cobb 500 broiler chicks. a total of 600 1-day-old cobb 500 broiler chicks with an average weight of 39 ± 0.50 g were randomly divided into five treatments. each treatment was further divided into four replicates. chicks were fed a basal diet based on corn and ...

this paper considers the generation of some interpretable fuzzy rules for assigning an amino acid sequence into the appropriate protein superfamily. since the main objective of this classifier is the interpretability of rules, we have used the distribution of amino acids in the sequences of proteins as features. these features are the occurrence probabilities of six exchange groups in the seque...

three experiments were conducted to evaluate the nutritional value of bitter vetch. experiment 1 was conducted to determine the metabolisable energy content of bitter vetch. sixteen adult leghorn roosters were used. forty grams of bitter vetch were precision-fed individually to 12 roosters. in addition, 4 birds were not fed and served as a control treatment in the measurement of metabolic fecal...

the synthesis and properties of new monoazo dyes derived from the diazonium salts of paminobenzoic acid, 3-trifluoromethyl aniline , 4-trifluoromethyl aniline are considered .theprepared compounds were characterized by uv-visible , ft-ir and h nmr spectroscopictechniques . the effect of varying solvent upon the absorption ability of p-amino benzoic acidcoupled with 4,4 —diethyl aniline , anilin...