Tertiary ethers are formed in a reaction between alcohols and alkenes. They are used in gasoline to enhance its burning and to reduce harmful exhaust emissions. They also have high octane rating, which is beneficial for gasoline blending. Regulations in regard to fuel composition and exhaust emissions are tightening and new, cleaner burning high octane gasoline components are of wide interest. ...

The acetalization of six different types of glycerol including pure, wet, and crude-like grade compounds of compositions simulating those of crude glycerols produced by the biodiesel manufacture, was carried out with two model ketones such as acetone and 2-butanone. The reaction was investigated under continuous-flow (CF) conditions through a comparative analysis of an already known acetalizati...

The hydrolysis of sodium borohydride as a source of hydrogen gas is studied at different mole ratios of H+ to NaBH4. The sulfonated porous carbon (SPC) is used as a source of hydrogen ion and catalyst. It is found that the sulfonated porous carbon exhibits high activity for the hydrolysis of NaBH4 to generate hydrogen gas at room temperature in comparison to Amberlyst-15 and Nafion-NR50. The ki...

This work deals with kinetics and chemical equilibrium studies of esterification reaction of ethanol with acetic acid.  The esterification reaction was catalyzed by an acidic ion exchange resin (Amberlyst-15) using a batch stirred tank reactor. The pseudo-homogenous and Eley-Rideal models were successfully fitted with experimental data. At first, Eley-Rideal model was examined for heterogeneous...

In this study we considered processes of treatment agricultural apple waste which is normally discarded. We show the effect various pre-treatment procedures on final catalytic performance to produce 5-HMF from real world biomass waste. Our potential steps, and their performance, provides valuable new insights can be used for development localised small scale valorization fruit The aimed convert...

in the chemical industry, process intensification is needed to meet important goals such as sustainable and eco-friendly processes. for esterification reaction the “produce more with less pollution” objective can be achieved by coupling reaction and separation in a so called integrated process. in this work a model for describing the esterification reaction of ethyl acetate in pervaporation mem...

the hydrolysis of sodium borohydride as a source of hydrogen gas is studied at different mole ratios of h+ to nabh4. the sulfonated porous carbon (spc) is used as a source of hydrogen ion and catalyst. it is found that the sulfonated porous carbon exhibits high activity for the hydrolysis of nabh4 to generate hydrogen gas at room temperature in comparison to amberlyst-15 and nafion-nr50. the ki...