Notable biological activities including brains protective have made carbohydrate esters as a topic of great interest over the past several decades. In this context, unimolecular treatment methyl α-L-rhamnopyranoside (3) with dibutyltin oxide gave corresponding 2,3-O-(dibutylstannylene) derivative which was then allowed to react 3-chlorobenzoyl chloride. The reaction regioselectively furnished 3...