A large number of sediment samples representing most of the active mud accumulation areas of the Gulf of Finland were studied for total cadmium, chromium, lead, mercury, arsenic, copper and zinc. The highest concentrations of metals were found in sediment surfaces in the easternmost part of the Gulf, which is influenced by the inflow of the Neva river and the loads of the city of St. Petersburg...

The 2.15-A resolution cocrystal structure of EcoRV endonuclease mutant T93A complexed with DNA and Ca2+ ions reveals two divalent metals bound in one of the active sites. One of these metals is ligated through an inner-sphere water molecule to the phosphate group located 3' to the scissile phosphate. A second inner-sphere water on this metal is positioned approximately in-line for attack on the...

Maghemite particles were synthesized by using a combined combustion method and sonochemical step. was used as carrier to prepare supported Pt Pd catalysts after deposition via The immediately ready be (metals catalytically active) for the 2,4-dinitrotoluene hydrogenation produce 2,4-toluenediamine. most active Pd/maghemite bimetallic Pd-Pt/maghemite. easily separable reaction due their magnetic...

After considering the particular problems of atmospheric pollution in megacities, i.e. agglomerations larger than 5 mio. inhabitants, with urbanization of World's population going on steadily, possibilities of active biomonitoring by means of green plants are discussed. Based on specific definitions of active and passive bioindication the chances of monitoring heavy metals in Sao Paulo megacity...

Doped graphene, a one-atom-thick but highly conductive sheet, provides us with an unprecedented platform to explore surface plasmon and two-dimensional optics in a regime that can hardly be obtained with noble metals or conventional electron gases. Theoretical calculations show that graphene surface plasmon (transverse magnetic mode) shows extraordinarily tight confinement and short wavelength....

Transition metal complexes are located at the active sites of a number of enzymes involved in intriguing biochemical reactions. These complexes can exhibit a wide variety of chemical reactivity due to the ease at which transition metals can adopt different coordination environments and oxidation states. Crystallography has been a powerful technique for examining the structure and conformational...

During the activation of the inactive dinitrogenase reductase from Rhodospirillum rubrum, an adenine-like molecules is lost and phosphate is found on both active and inactive forms of the protein. ATP and divalent metals are required for activation of the reduced protein, but ATP is not required for activation of phenazine methosulfate-oxidized dinitrogenase reductase. Snake venom diesterase an...

The identification of the active sites in heterogeneous catalysis requires a combination of surface sensitive methods and reactivity studies. We determined the active site for hydrogen evolution, a reaction catalyzed by precious metals, on nanoparticulate molybdenum disulfide (MoS2) by atomically resolving the surface of this catalyst before measuring electrochemical activity in solution. By pr...

A photoelectrochemical study was made to compare Zr, Ti, Zn, Sn, Fe, and Cu in 1 N sulfuric acid and/or 1 N KOH. This group includes spontaneously passive, active-passive, and nonpassive metals. The apparent direct and indirect bandgaps and the flatband potentials were measured for the anodic oxides of each metal. (The bandgaps and flat-band potentials can be used to identify the anodic oXide.)...