The host-guest complexes of resorcin[4]arenes with small molecules in organic solutions are examined using modern NMR spectroscopic methods. The complexation of glutaric acid and beta-methyl d-glucopyranoside in chloroform were investigated through 2D COSY, 2D NOESY, 1D NOE, and diffusion-ordered NMR spectroscopy (DOSY) techniques. These methods indicate that the complex is a self-assembled cap...

We have recently demonstrated that magnetic field gradients in combination with frequency selective pulses, can be employed to collect a complete multi-dimensional NMR spectrum within a single scan. Following similar guidelines, field gradients could also be exploited to parallelize other types of NMR experiments where the final results arise from the collection and analysis of a series of time...

Surfactant-templated layered silicates are shown to possess complex compositional, structural, and dynamic features that manifest rich and interrelated order and disorder at molecular length scales. Temperature-dependent 1D and 2D solid-state 29Si NMR measurements reveal a chemical-exchange process involving the surfactant headgroups that is concomitant with reversible broadening of 29Si NMR li...

Laboratorium für Anorganische Chemie der Universität Bayreuth, Postfach 101251, D-8580 Bayreuth Z. Naturforsch. 42b, 703-706 (1987); received January 15, 1987 Reverse 2D 'H{N} NMR Spectra, Phosphane Complexes, Inorganic Ring System PS2N3, X-Ray The inorganic ring system RPNSNSNH linked to the [Cr(CO)5] fragment [R = T3u (1), NH2 (2)], has been studied by reverse two-dimensional, 2D , 'H{N} NMR ...

A phytochemical investigation on the essential oil of Thuja orientalis resulted in the isolation and identification of three new sesquiterpenes, 3α-methoxy-4α-epoxythujopsane (1), Δ³,¹⁵-4β-epoxythujopsene (2), and Δ³,⁴-thujopsen-2,15-diol (3), together with eight known sesquiterpenoids (4-11). The structures of these new compounds were elucidated based on spectroscopic data analyses including e...

Four new compounds 1-4 were obtained from an oxidative coupling reaction of (E)-isorhapontigenin using FeCl(3) as oxidant. Their structures and stereochemistry were determined on the basis of spectroscopic evidence [UV, IR, MS, (1)H-, (13)C-NMR, NOE and 2D NMR], and their possible formation mechanisms were also discussed, respectively.

Two aphorpine alkaloids, (+)-lirinine 1 and (+)-lirioferine 2 and two bezylisoquinoline alkaloids (+)reticuline 3 and (-)-N-Methylisococlaurine 4 were isolated from bark of Cryptocarya crassinervia. The structures were elucidated by spectral analysis, including 1D-NMR (H, C, DEPT), 2D-NMR (COSY, HMQC, HMBC), UV, IR, and MS and comparison with the published data.

A New pregnane type Alkaloid named Sracosalgminol [(20S)-20-(dimethylamino)-3β-methoxy-16β-hydroxyl-pregn-5-ene] was isolated from sarcococca saligna and its structure was established on the basis of spectroscopic techniques includingH,13C-NMR and inverse 2D-NMR techniques (DEPT,HMQC and HMBC) UV,MS etc.

We demonstrate the application of Compressed Sensing-NMR to decrease the data acquisition time of 2D COSY NMR from >5 h to ∼1.5 h such that the kinetics of a reaction are followed, along with identification of intermediate and product species.

A New Alkaloid named Sracosalgnenone [ (20S) -20(dimethylamino) -3β-tigoloyl-pregn-5, 16-diene-4-one] was isolated from sarcococca saligna and its structure was established on the basis of spectroscopic techniques includingH, C-NMR and inverse 2D-NMR techniques (DEPT, HMQC and HMBC) UV, MS etc.