Hydrolysis of polycarbonate (PC) was studied using ionic liquid 1-butyl-3-methylimidazolium acetate ([Bmim][Ac]) as a catalyst. The influences of temperature, time, water dosage and [Bmim][Ac] dosage on the hydrolysis reaction were examined. Under the conditions of temperature 140°C, reaction time 3.0 h, m([Bmim][Ac]):m(PC)=1.5:1 and m(H(2)O):m(PC)=0.35:1, the conversion of PC was nearly 100% a...

A polyoxomolybdate inorganic-organic hybrid crystal was synthesized with deprotonatable ionic-liquid surfactant. 1-dodecylimidazolium cation was employed for its synthesis. The hybrid crystal contained δ-type octamolybdate (Mo₈) isomer, and possessed alternate stacking of Mo₈ monolayers and interdigitated surfactant bilayers. The crystal structure was compared with polyoxomolybdate hybrid cryst...

The reflection-absorption infrared (RAIRS) spectra of 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide ([EMIM]Tf(2)N) are presented for liquid as well as for amorphous and crystalline solid films. The liquid and amorphous films show rather similar spectra, indicating that the film structure is similar in both cases. On the other hand, these spectra differ considerably from those of...

ABSTRACT B3LYP/6-31++G(d) calculations indicated that the reaction of (2E)-3-phenyl-2-nitroprop-2-enenitrile with cyclopentadiene catalyzed by cations of 1,3-dialkylimidazolium ionic liquid shall not take place according to the classical scheme of one-step [2+4] Diels-Alder cycloaddition. Along the path finally leading to bicyclo[2.2.1]hept-5-ene (norbornene) with a nitro group in endo orientat...

A small series of indol-3-yl-oxoacetamides was synthesized starting from the literature known N-(adamantan-1-yl)-2-(5-(furan-2-yl)-1-pentyl-1H-indol-3-yl)-2-oxoacetamide (5) by substituting the 1-pentyl-1H-indole subunit. Our preliminary biological evaluation showed that the fluorinated derivative 8 is a potent and selective CB₂ ligand with Ki = 6.2 nM.

The enthalpies of vaporisation, Δ(vap)H(298), of seven ionic liquids (ILs) (four imidazoliums, a pyridinium, a phosphonium and an isouronium) have been determined by temperature programmed desorption using line of sight mass spectrometry. They were: 1-ethyl-3-methylimidazolium bis(pentafluoroethyl)phosphinate, [C(2)C(1)Im][PO(2)(C(2)F(5))(2)]; 1-butyl-3-methylimidazolium octylsulfate, [C(4)C(1)...

An efficient K3PO4-mediated synthesis of unsymmetrical diaryl ethers using the ionic liquid [Bmim]BF4 (1-butyl-3-methylimidazolium tetrafluoroborate) as solvent has been developed. The procedure involves consecutive deprotection of aryl methane-sulfonates and a nucleophilic aromatic substitution (S(N)Ar) with activated aryl halides.

This work concerns the effect of fillers and ionic liquids on cure characteristics natural rubber (NR) compounds, as well mechanical thermal properties vulcanizates. Three types white filler were applied, such cellulose, nanosized silica hydrotalcite, to modify performance NR composites. Additionally, (ILs) with bromide anion different cations, i.e., 1-butyl-3-methylimidazolium (Bmi) 1-butyl-3-...

In this work, the ethanol fuel dehydration process was optimized using Aspen Plus? simulator and a multivariate statistical technique based on desirability function. The suitability of ionic liquids 1-methylimidazolium chloride ([Mim][Cl]), 1-ethyl-3-methylimidazolium ([Emim][Cl]), 1-butyl- -3-methylimidazolium ([Bmim][Cl]) 1-hexyl-3-methylimidazolium ([Hmim][Cl]), as extractive distillation en...

In this paper, aggregation behaviors of aqueous solutions of short chain hydrophilic Ionic Liquids (ILs), 1 – allyl - 3 - methylimidazolium chloride ([Amim]Cl), 1 - ethyl - 3 - methylimidazolium chloride ([Emim]Cl), 1 - butyl - 3 - methylimidazolium chloride ([Bmim]Cl), 1 - butyl - 3 - methylimidazolium tetrafluoroborate ([Bmim]BF4) were investigated using conductivity and laser ...