p-tert-Butylcalix[6]arene hexaacetic acid is in a symmetric cone conformation in CHCl3, but it becomes conformationally flexible in CHCl3/CH3CN (1 : 1). In this mixture the host has a strong binding affinity towards Pb(II) and instantly forms a complex of low symmetry--shortly thereafter structural reorganization occurs resulting in a high symmetry complex of Pb(II) in an octahedral cage of car...

Various digestion procedures were carefully investigated and accurately evaluated with respect to their effect on the analysis of cereals and cereal flours. Multielement methods were selected and well developed for the determination of essential (Cr, Cu, Fe, Mg, Mn, and Zn), nonessential (Ag, Al, Ba, Bi, In, and Ga), and toxic (Cd and Pb) minor and trace elements by inductively coupled plasma-a...

Rouf, M. A. (Washington State University, Pullman). Spectrochemical analysis of inorganic elements in bacteria. J. Bacteriol. 88:1545-1549. 1964.-Quantitative spectrochemical analyses of inorganic elements in the vegetative cells of Escherichia coli, Sphaerotilus natans, Micrococcus roseus, Bacillus cereus, and the spores of B. cereus were made. The following elements were found to be present i...

Amanita ponderosa are wild edible mushrooms that grow in some microclimates of Iberian Peninsula. Gastronomically this species is very relevant, due to not only the traditional consumption by the rural populations but also its commercial value in gourmet markets. Mineral characterisation of edible mushrooms is extremely important for certification and commercialization processes. In this study,...

Two homologous series of cyclically twinned sulphosalt structures are defined in the present paper, with different atomic configurations around the site of sixand threefold axes. The zinckenite homologous series, M6+x+N(N+S) A12+N(N+7), contains zinckenite, a Pb-Sb sulphosalt, and sulphohalogenides of Bi and Pb. The Ba Bi sulphide homologous series, M12+x+N(N+S) A18+N(N+7), contains complex sul...

The atomic structure of ordered domains in Ba~Mg1/3Nb2/3)O3 and La-doped and undoped Pb~Mg1/3Nb2/3)O3 is studied by high-resolution Z-contrast imaging. The ordered domain structure in both doped and undoped Pb~Mg1/3Nb2/3)O3 is determined to be in agreement with the charge balanced random-layer model and inconsistent with the space-charge model. It is shown that La doping in Pb~Mg1/3Nb2/3)O3 enh...

Cadmium (Cd) and lead (Pb) are toxic even in small quantities decrease crop yields. They easily absorbed by plant roots, thus enter the food chain, risking human health. Radish (Raphanus sativus L.) is a widely consumed root vegetable Korea. Therefore, it important to screen for radish cultivar that exhibits low Cd Pb accumulation elucidate tolerance mechanism. In this study, we determined effe...

We report Sr, Pd and Ag abundances for a sample of metal-poor field giants and analyze a larger sample of Y, Zr, and Ba abundances. The [Y/Zr] and [Pd/Ag] abundance ratios are similar to those measured for the r-process-rich stars CS 22892-052 and CS 31082-001. The [Pd/Ag] ratio is larger than predicted from the solar-system r-process abundances. The constant [Y/Zr] and [Sr/Y] values in the fie...