نتایج جستجو برای: اکسیم oxime

تعداد نتایج: 2718  

پایان نامه :وزارت علوم، تحقیقات و فناوری - دانشگاه علوم پایه دامغان - دانشکده علوم پایه دامغان 1391

در این پایان نامه با توجه به اهمیت اکسیم ها در سنتزهای آلی، صنعت و نیز پزشکی و از طرف دیگر لزوم به-کارگیری هرچه بیشتر و دقیق تر مولفه های شیمی سبز در دنیای کنونی، تبدیل مستقیم الکل ها به اکسیم ها با استفاده از کاتالیزور تری کلرو ایزوسیانوریک اسید(tcca) و به کمک نمک هیدروکسیل آمین هیدروکلرید (nh3+ohcl- ) در شرایط بدون حلال و با بهره های عالی ارائه می شود. از طرفی در این تحقیق به دلیل اهمیت زیاد...

Journal: :Acta Crystallographica Section E Structure Reports Online 2011

Journal: :Inorganics (Basel) 2023

A series of four Werner-type complexes Pd(II) and Pt(II) with planar, isomeric conjugated aromatic naphtoquinone oximes were synthesized for the first time. These ligands 1-oxime-2-naphtoquinone (HL1) 2-oxime-1-napthoquinone (HL2). Compounds characterized using thermal analysis, spectroscopic methods, X-ray analysis. TG/DSC data collected pure starting organic ligands, their complexes, indicate...

Journal: :Molecular bioSystems 2014
Rabindranath Lo Bishwajit Ganguly

Organophosphorus nerve agents are highly toxic compounds which strongly inhibit acetylcholinesterase (AChE) in the blood and in the central nervous system (CNS). Tabun is one of the highly toxic organophosphorus (OP) compounds and is resistant to many oxime drugs formulated for the reactivation of AChE. The reactivation mechanism of tabun-conjugated AChE with various drugs has been examined wit...

Akriti Kaura Girish Thunga, Rama Mylapuri Sreedharan Nair Sudha Vidyasagar Sureshwar Pandey Vijayanarayana Kunhikatta

Organophosphate (OP) poisoning is one of the most common causes of poisoning in developing countries especially in Southeastern Asia. Poisoning with phosphorus-containing organic chemicals or OP compounds can be managed with antidotes like oximes which are potential reactivators of acetylcholinesterase (AChE). The efficacy of oxime therapy in OP poisoned patients mainly depends upon various fac...

Journal: :Berichte der deutschen chemischen Gesellschaft 1889

Journal: :Theoretical Chemistry Accounts 2021

Interstellar formations and significances of formamide as a possible prebiotic precursor, for many complex organic molecules life are well studied in recent times. In this work, computational studies (B3LYP, wB97xD, MP2, CCSD(T)) have been carried out to study the formation mechanism formamide, from HNCO + H2, via concerted paths. Beside well-studied, Direct Route, three new routes, imine, carb...

2011
Xiao-Hui Deng Jing-Wen Ran

In the title dinuclear compound, [Zn(2)(C(6)H(6)N(3)O)(2)(C(6)H(7)N(3)O)(2)](NO(3))(2), the Zn(II) cation is N,N'-chelated by one pyridine-2-carboxamide oximate anion and one pyridine-2-carboxamide oxime mol-ecule, and is further bridged by an oxime O atom from the adjacent pyridine-2-carboxamide oximate anion, forming a distorted trigonal bipyramidal coordination. Two pyridine-2-carboxamide ox...

2016
Karolina Wieszczycka Marta Krupa Aleksandra Wojciechowska Irmina Wojciechowska Andrzej Olszanowski

In present paper the equilibrium of cobalt extraction with 1-(2-pyridyl)tridecan-1-one oxime from the chloride/sulphate solutions was studied. The presented results indicated that extraction depends on a number of process variables, including the pH, metal and Cl- concentration in the aqueous feed, and concentration of the oxime in the organic phase. The created cobalt-complexes with the 2-pyri...

2009
Guang-Dong Huang Jian-Wei Zou Wen-Na Zhao Shu-Min Zhao

The title compound, C(14)H(13)Cl(2)NO(3), was obtained as the product of an attempted synthesis of herbicidally active compounds containing oxime ether and cyclo-hexenone groups. In the crystal structure, the mol-ecule adopts an endocyclic enol tautomeric form and the cyclo-hexene ring adopts a distorted envelope form. The oxime ether group has an E configuration, with the meth-oxy group anti t...

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